• 专利标题:   Preparing alkylamine-functionalized graphene used to prepare graphene/polymer composite material, by adjusting pH-value of graphene oxide aqueous solution using acid, and then adding acid ethanol solution of long-chain alkylamine.
  • 专利号:   CN107722352-A
  • 发明人:   LU H, RUAN Y
  • 专利权人:   ZHEJIANG SHANYU TECHNOLOGY CO LTD
  • 国际专利分类:   C01B032/184, C01B032/194, C08K003/04, C08K009/04, C08L101/00, C08L023/00
  • 专利详细信息:   CN107722352-A 23 Feb 2018 C08K-009/04 201820 Pages: 8 Chinese
  • 申请详细信息:   CN107722352-A CN11077331 06 Nov 2017
  • 优先权号:   CN11077331

▎ 摘  要

NOVELTY - The preparation method of long-chain alkylamine-functionalized graphene involves adding an acid to a graphene oxide aqueous solution to adjust the pH-value of solution to less than 7, adding an ethanol solution of long-chain alkylamine to the graphene oxide aqueous solution with the pH-value adjusted, evenly mixing to obtain a mixed solution, then performing grafting reaction and chemical reduction under heating conditions, separating the resulting mixed reaction solution to remove unreacted long-chain alkylamine, and washing with ethanol. USE - The method is useful for preparing long-chain alkylamine-functionalized graphene, which is useful for preparing graphene/polymer composite material. ADVANTAGE - The method enables simple preparation of long-chain alkylamine-functionalized graphene under mild reaction condition with strong practicability in an environmentally-friendly manner. DETAILED DESCRIPTION - The preparation method of long-chain alkylamine-functionalized graphene involves adding an acid to a graphene oxide aqueous solution to adjust the pH-value of solution to less than 7, adding an ethanol solution of long-chain alkylamine to the graphene oxide aqueous solution with the pH-value adjusted, evenly mixing to obtain a mixed solution, then performing grafting reaction and chemical reduction under heating conditions, separating the resulting mixed reaction solution to remove unreacted long-chain alkylamine, washing with ethanol to obtain an ethanol solution or a slurry material of long-chain alkylamine functionalized graphene, and drying to obtain product. An INDEPENDENT CLAIM is included for long-chain alkylamine-functionalized graphene prepared by the above method.