• 专利标题:   Method for preparing nano-graphene/sulfur composite material for use as lithium sulfur battery positive pole material, involves preparing graphene dispersion, preparing nano-graphene, followed by adding sulfur powder, milling and heating.
  • 专利号:   CN105047893-A, CN105047893-B
  • 发明人:   GAO Y, YIN G, ZHANG W, ZUO P
  • 专利权人:   HARBIN INST TECHNOLOGY, HARBIN INST TECHNOLOGY
  • 国际专利分类:   H01M010/0525, H01M004/133, H01M004/38, H01M004/66
  • 专利详细信息:   CN105047893-A 11 Nov 2015 H01M-004/38 201612 Pages: 10 Chinese
  • 申请详细信息:   CN105047893-A CN10485833 10 Aug 2015
  • 优先权号:   CN10485833

▎ 摘  要

NOVELTY - A nano-graphene/sulfur composite material preparing method involves preparing graphene dispersion, preparing nano-graphene by dispersing metal oxide nanoparticles in deionized water ultrasonically, mixing, incubating, cooling, solidifying, transferring to freeze dryer and drying to obtain nano-graphene. Sulfur powder is added to organic solvent, stirred until completely dissolved, added with nano-graphene, evaporated to dryness to obtain product. The product is allowed for ball milling, subjected for heat treatment under inert atmosphere protection to obtain the finished product. USE - Method for preparing nano-graphene/sulfur composite material for use as lithium sulfur battery positive pole material (claimed). ADVANTAGE - The method enables preparing composite material with high specific capacity and good cycle stability, in simple, easy and cost effective manner. DETAILED DESCRIPTION - A nano-graphene/sulfur composite material preparing method involves preparing graphene dispersion by adding reducing agent in graphene oxide under water bath at 70-100 degrees C, washing until neutral graphene, dispersing in deionized water to obtain graphene dispersion, preparing nano-graphene by dispersing metal oxide nanoparticles in deionized water ultrasonically, mixing, incubating, cooling, solidifying, transferring to freeze dryer and drying to obtain nano-graphene. Sulfur powder is added to organic solvent, stirred until completely dissolved, added with nano-graphene, evaporated to dryness to obtain product. The product is allowed for ball milling, subjected for heat treatment under inert atmosphere protection to obtain the finished product.