• 专利标题:   Preparing reduced graphene oxide coated sulfide/bimetal oxide composite material, comprises e.g. adding cobalt salt, iron salt, 2,5-dihydroxyterephthalic acid, polyvinylpyrrolidone and graphene oxide into sealed container, and calcining.
  • 专利号:   CN111606320-A
  • 发明人:   XIA Z, JIA X, REN C, CHEN S
  • 专利权人:   UNIV NORTHWEST
  • 国际专利分类:   B82Y030/00, B82Y040/00, C01B032/184, C01G051/00, C01G051/04, H01G011/30, H01G011/36, H01G011/46
  • 专利详细信息:   CN111606320-A 01 Sep 2020 C01B-032/184 202077 Pages: 17 Chinese
  • 申请详细信息:   CN111606320-A CN10482694 01 Jun 2020
  • 优先权号:   CN10482694

▎ 摘  要

NOVELTY - Preparing reduced graphene oxide coated sulfide/bimetal oxide composite material, comprises adding cobalt salt, iron salt, 2,5-dihydroxyterephthalic acid, polyvinylpyrrolidone and graphene oxide as raw materials into a sealed container, adding solvent to carry out the solvothermal reaction to generate cobalt-iron-graphene oxide complex, then mixing cobalt-iron-graphene oxide complex with sublimation sulfur and placing in a tube furnace, and calcining under sublimated sulfur and inert gas atmosphere to obtain final product. USE - The reduced graphene oxide coated sulfide/bimetal oxide composite material is useful as electrode material in supercapacitor energy storage material (claimed construction of supercapacitors). ADVANTAGE - The nanocomposite material has hierarchical porous sheet-type nano-flower structure. The constructed supercapacitor has high energy density and high power density, prolonged service life; and overcomes the difficulty of preparing traditional sulfide oxide composite materials; The method has characteristics of high energy consumption and low repeatability. DETAILED DESCRIPTION - Preparing reduced graphene oxide coated sulfide/bimetal oxide composite material, comprises adding cobalt salt, iron salt, 2,5-dihydroxyterephthalic acid, polyvinylpyrrolidone and graphene oxide as raw materials into a sealed container, adding solvent to carry out the solvothermal reaction to generate cobalt-iron-graphene oxide complex of formula (Co2.75Fe-MOF-74-GO), then mixing cobalt-iron-graphene oxide complex with sublimation sulfur and placing in a tube furnace, and calcining under sublimated sulfur and inert gas atmosphere to obtain final product. An INDEPENDENT CLAIM is also included for reduced graphene oxide coated sulfide/bimetal oxide composite material prepared by method.