• 专利标题:   Preparing sodium-ion battery cathode material, comprises e.g. reacting concentrated nitric acid with graphene nanosheet slurry, reacting with nickel(II) nitrate and cobalt(II) nitrate in methanol, and reacting with methanol solution of 2-methylimidazole and thioacetamide solution.
  • 专利号:   CN114613999-A
  • 发明人:   MENG X, ZHANG K, BI S, FAN S, LIU H
  • 专利权人:   WEIHAI YUNSHAN TECHNOLOGY CO LTD, HARBIN INST TECHNOLOGY AT WEIHAI
  • 国际专利分类:   B82Y030/00, H01M010/0525, H01M004/36, H01M004/58, H01M004/62
  • 专利详细信息:   CN114613999-A 10 Jun 2022 H01M-004/58 202264 Chinese
  • 申请详细信息:   CN114613999-A CN10258130 16 Mar 2022
  • 优先权号:   CN10258130

▎ 摘  要

NOVELTY - Preparing sodium-ion battery cathode material i.e. nickel-cobalt-sulfide-graphene nanosheet (I), comprises (1) mixing concentrated nitric acid and graphene nanosheet slurry, and reacting to obtain activated graphene nanosheet (GNs), (2) mixing nickel(II) nitrate and cobalt(II)nitrate with GNs methanol solution to obtain solution A and mixing methanol solution of 2-methylimidazole with solution A to obtain solution B, and (3) mixing thioacetamide solution with solution B and reacting to obtain final product. USE - The method is useful for preparing cathode material for sodium-ion battery (claimed). ADVANTAGE - The method: utilizes metal-organic frameworks as sacrificial templates to in situ grow hollow nanocages nickel-cobalt-sulfide (NiCo2S4) on the surface of graphene nanosheets (GNs) by one-step solvothermal method; is simple; has excellent crystallinity; and realizes uniform in-situ growth and hollow nano-cage structure on the surface of graphene nano-sheets. (I): exhibits excellent cycling and rate performance as the cathode material for sodium-ion batteries; and has excellent rate performance under different current densities. DETAILED DESCRIPTION - Preparing sodium-ion battery cathode material i.e. nickel-cobalt-sulfide-graphene nanosheet of formula ((NiCo2S4GNs) (I), comprises (1) mixing concentrated nitric acid and graphene nanosheet slurry, and reacting to obtain activated graphene nanosheet (GNs), (2) mixing nickel(II) nitrate and cobalt(II) nitrate with GNs methanol solution to obtain solution A and mixing methanol solution of 2-methylimidazole with solution A to obtain solution B, and (3) mixing thioacetamide solution with solution B and reacting to obtain final product.