• 专利标题:   Preparing bismuth vanadate electrode co-modified by metal organic frameworks and hydrothermal reduced graphene oxide in field of photocatalysis, involves dissolving bismuth nitrate in nitric acid, and adding ammonium metavanadate.
  • 专利号:   CN111348728-A
  • 发明人:   WANG Q, LIU Y, WENG W, JIAN Y, ZHU J, ZHANG C
  • 专利权人:   UNIV ZHEJIANG GONGSHANG
  • 国际专利分类:   C02F001/30, C02F001/46, C02F101/34
  • 专利详细信息:   CN111348728-A 30 Jun 2020 C02F-001/46 202062 Pages: 10 Chinese
  • 申请详细信息:   CN111348728-A CN10218954 25 Mar 2020
  • 优先权号:   CN10218954

▎ 摘  要

NOVELTY - Preparing bismuth vanadate (BiVO4) electrode co-modified by metal organic frameworks (MOF) and hydrothermal reduced graphene oxide (HrGO) involves dissolving bismuth nitrate in nitric acid, adding ammonium metavanadate and polyvinyl alcohol, and ultrasonically obtaining seed solution. The seed solution is smeared on clean conductive glass, dried, calcined and taken out as base electrode. The bismuth nitrate and ammonium metavanadate is dissolved in nitric acid, placed into substrate electrode, subjected to hydrothermal reaction, and calcined after reaction to obtain BiVO4 electrode. The 2-aminoterephthalic acid is dissolved in dimethylformamide (DMF) and tetrabutyl titanate in methanol, mixed and stirred. The reduced graphene oxide obtained by hydrogen plasma treatment is added and mixed uniformly. The BiVO4 electrode is placed into solvothermal reaction to obtain BiVO4/NH2MIL125-HrGO composite film electrode. USE - Method for preparing BiVO4 electrode co-modified by MOF and HrGO used in field of photocatalysis (claimed).