• 专利标题:   Non-migrating graphene oxide grafted antioxidant prepared by e.g. dissolving graphene oxide in thionyl chloride, adding thionyl chloride-modified graphene oxide into dimethylformamide, separating and drying.
  • 专利号:   CN108503888-A
  • 发明人:   HUANG G, ZHENG J, ZHOU J, WEI L, WEI H, ZHU Y
  • 专利权人:   UNIV SICHUAN
  • 国际专利分类:   C08K009/04, C08K009/02, C08K003/04, C08L007/00
  • 专利详细信息:   CN108503888-A 07 Sep 2018 C08K-009/04 201865 Pages: 11 Chinese
  • 申请详细信息:   CN108503888-A CN10266103 28 Mar 2018
  • 优先权号:   CN10266103

▎ 摘  要

NOVELTY - Non-migrating graphene oxide grafted antioxidant is claimed. The antioxidant is obtained by grafting modification of graphene oxide with 4-aminodiphenylamine to form hydroxy group in carboxy group of graphene oxide by R group substitution, where graft ratio of R group is 7-15 wt.%. USE - Used as non-migrating graphene oxide grafted antioxidant. DETAILED DESCRIPTION - Non-migrating graphene oxide grafted antioxidant is claimed. The antioxidant is obtained by grafting modification of graphene oxide with 4-aminodiphenylamine to form hydroxy group in carboxy group of graphene oxide by R group substitution, where graft ratio of R group is 7-15 wt.%. R = 4-(phenylamino)phenylamino. An INDEPENDENT CLAIM is also included for preparing non-migrating graphene oxide grafted antioxidant comprising (i) dissolving graphene oxide in thionyl chloride, then refluxing for 1-3 hours, separating reaction product, washing and removing thionyl chloride to obtain thionyl chloride modified graphene oxide, and (ii) adding thionyl chloride-modified graphene oxide into dimethylformamide, and ultrasonically dissolving thionyl chloride-modified graphene oxide to obtain solution of thionyl chloride modified graphene oxide having concentration of 0.5-1 mg/ml, dissolving 4-aminodiphenylamine in dimethylformamide, and then mixing thionyl chloride-modified graphene oxide solution with the 4-aminodiphenylamine solution, controlling to form mixture, where mass ratio between thionyl chloride-modified graphene oxide and 4-aminodiphenylamine is 1:15-30, performing re-flow reaction for 40-60 hours, performing solid-liquid separation, soaking obtained solid phase in absolute ethanol, and soaking solid product after, separating and drying.