• 专利标题:   Preparing magnetic reduced graphene oxide composite material used to remove quinolone antibiotic from water, comprises mixing oxidized graphene with ethylene glycol, and adding sodium citrate, iron(III) chloride hexahydrate and urea.
  • 专利号:   CN104096536-A
  • 发明人:   WANG Y, TANG Y, XIAO L
  • 专利权人:   UNIV TONGJI
  • 国际专利分类:   B01J020/20, B01J020/28, B01J020/30, C02F009/12
  • 专利详细信息:   CN104096536-A 15 Oct 2014 B01J-020/20 201503 Pages: 10 Chinese
  • 申请详细信息:   CN104096536-A CN10111541 01 Apr 2013
  • 优先权号:   CN10111541

▎ 摘  要

NOVELTY - Preparing a magnetic reduced graphene oxide composite material comprises: (1) mixing oxidized graphene with ethylene glycol and then ultrasonically treating; (2) dissolving sodium citrate in ethylene glycol mixture, and heating the mixture; (3) mixing iron(III) chloride hexahydrate and urea with the mixture and then stirring to obtain a mixed solution of ethylene glycol; (4) reacting the mixed solution in a reactor and then heating, and cooling the heated mixture; and (5) centrifuging the reacted mixture, and washing the mixture and freeze-drying. USE - The method is useful for preparing a magnetic reduced graphene oxide composite material that is useful for removing quinolone antibiotic from water (all claimed). ADVANTAGE - The method is capable of preparing a magnetic reduction graphene oxide in a simple and cost-effective manner with high purity. DETAILED DESCRIPTION - Preparing a magnetic reduced graphene oxide composite material comprises: (1) mixing oxidized graphene with ethylene glycol and then ultrasonically treating; (2) dissolving sodium citrate in ethylene glycol mixture, and heating the mixture; (3) mixing iron(III) chloride hexahydrate and urea with the mixture and then stirring to obtain a mixed solution of ethylene glycol; (4) reacting the ethylene glycol mixed solution in a reactor and then heating, and cooling the heated mixture; and (5) centrifuging the reacted mixture, and washing the mixture and freeze-drying to obtain magnetic reducing graphene oxide. An INDEPENDENT CLAIM is included for removing quinolone antibiotic form water comprising: adding graphene oxide with an aqueous solution having a quinolone antibiotic concentration of 1-5 mg/l, where the graphene oxide concentration in the aqueous solution is 10-200 mg/l; and subjecting the mixture to a magnetic separation process at a pH of 6.5-7.5.