• 专利标题:   Preparation of graphene/ceramic nano-fiber/polyvinyl alcohol hybrid gas gel comprises electrospinning precursor and polyethylene pyrrolidone powder into a mixed solution of tetrahydrofuran and absolute ethanol, placing uniform solution into microwave oven for irradiation and directionally freezing.
  • 专利号:   CN114409954-A
  • 发明人:   LI F, TANG Y, HUO Y, ZHAO K
  • 专利权人:   UNIV XIAN TECHNOLOGY
  • 国际专利分类:   C08J009/28, C08K003/04, C08K007/04, C08K007/10, C08L029/04, H05K009/00
  • 专利详细信息:   CN114409954-A 29 Apr 2022 C08J-009/28 202282 Chinese
  • 申请详细信息:   CN114409954-A CN11495057 08 Dec 2021
  • 优先权号:   CN11495057

▎ 摘  要

NOVELTY - Preparing ceramic nanofiber/graphene alcohol hybrid gas gel comprises (i) electrospinning precursor and polyethylene pyrrolidone powder into a mixed solution of tetrahydrofuran and absolute ethanol to obtain a precursor, (ii) adding ceramic nano fiber to the mixed solution obtained in step (i), and stirring to obtain uniform solution, (iii) placing the uniform solution into a 500 W microwave oven for irradiation for 1 g, taking out and directionally freezing, dry finishing, placing in a 700 W argon atmosphere for microwave irradiation again for 30 seconds to obtain graphene/ceramic nano fiber/polyvinyl alcohol hybrid gel. USE - Preparation method of graphene/ceramic nano- fiber/polyvinyl alcohol hybrid gas gel used in super capacitor, lithium ion battery, sensor, electromagnetic wave absorbing/shielding and environment repairing field. ADVANTAGE - The method enables to prepare graphene/ceramic nano-fiber/polyvinyl alcohol hybrid gas gel, which has a three-dimensional porous structure, capable of providing more multiple reflection and scattering effect, dissipating the electromagnetic wave in the material, at the same time, enhancing the conductivity of the graphene, and further enhancing conductivity loss of gas gel improving the absorption performance of electromagnetic wave. The aerogel prepared by the method has a typical low density, super elasticity, good heat insulation performance and excellent minimum reflection loss, the wave absorbing performance is more than -60dB, the absorption bandwidth is greater than -7 GHz, and the aerogels have a typical high density, high elasticity and good heat insulating performance.