• 专利标题:   Reduced grapheme oxide-coated platinum/tin dioxide nanoparticle cluster for preparing gas sensor that is utilized in e.g. methanol gas detection, comprises distributing platinum atoms on surface of tin dioxide and coating graphene oxide.
  • 专利号:   CN108318510-A, WO2019136926-A1
  • 发明人:   CI L, PENG R, CHEN J, LI D, HOU G
  • 专利权人:   UNIV SHANDONG, UNIV SHANDONG
  • 国际专利分类:   G01N023/20, G01N023/20091, G01N023/22, G01N027/04
  • 专利详细信息:   CN108318510-A 24 Jul 2018 G01N-023/20 201857 Pages: 15 Chinese
  • 申请详细信息:   CN108318510-A CN10019257 09 Jan 2018
  • 优先权号:   CN10019257

▎ 摘  要

NOVELTY - A reduced grapheme oxide-coated platinum/tin dioxide nanoparticle cluster, comprises distributing uniformly platinum atoms on surface of tin dioxide to form an inner core and coating a reduced graphene oxide as a shell on surface of entire core, where the nanoparticle cluster is a core-like shell composite structure. USE - Reduced grapheme oxide-coated platinum/tin dioxide nanoparticle cluster for preparing gas sensor that is utilized in methanol gas detection, environmental detection, production safety detection, and disaster prevention. ADVANTAGE - The reduced grapheme oxide-coated platinum/tin dioxide nanoparticle cluster has low sensitivity, high temperature and, high sensitive detection, high stability, and can be prepared in simple, controllable and low in production cost. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for the following: (1) a method for preparing a reduced graphene oxide-coated platinum/tin dioxide nanoparticle cluster, involving taking a certain amount of water-soluble tin compound, dissolving in a solvent, stirring to obtain a uniform transparent solution, mixing a certain amount of dimethylformamide with the transparent solution to obtain a mixed solution, adding the graphene oxide powder to the deionized water, ultrasonically dispersing and performing a reduction treatment with a hydroiodic acid solution to obtain a reduced graphene oxide solution, adding a certain amount of chloroplatinic acid solution to the mixed solution, adding a basic substance, adjusting pH of the solution to alkaline to obtain a milky white precursor solution, mixing the reduced graphene oxide solution with the precursor solution, and carrying out hydrothermal synthesis reaction in a container lined with polytetrafluoroethylene, centrifuging a solution, after separation with ethanol and deionized water, washing, centrifuging, and rinsing to obtain a gelatinous product, drying the gelatinous product by two-step drying method and annealing to obtain the finished product (2) a method for preparing a gas sensor, involving coating a gelatinous product onto ceramic substrate by a spin coating process to obtain a ceramic substrate coated with a gel film,subjecting to a two-step drying method, and annealing to obtain annealed ceramic substrate, depositing an gold electrode on the annealed ceramic substrate using a standard photolithography process or a metal deposition technique to obtain the finished product.