• 专利标题:   Graphene/silver particle composite nanofiltration membrane used e.g. in preparing water flux device, is membrane like structure formed by uniformly dispersing nano silver particles in graphene layer, and comprises silver and graphene.
  • 专利号:   CN107233803-A
  • 发明人:   HUANG L, WANG Y, LIU G, TANG J, LI H
  • 专利权人:   UNIV QINGDAO
  • 国际专利分类:   B01D061/00, B01D067/00, B01D069/12, B01D071/02, B22F009/24, C02F001/44
  • 专利详细信息:   CN107233803-A 10 Oct 2017 B01D-069/12 201774 Pages: 14 Chinese
  • 申请详细信息:   CN107233803-A CN10409649 02 Jun 2017
  • 优先权号:   CN10409649

▎ 摘  要

NOVELTY - A graphene/silver particle composite nanofiltration membrane is membrane like structure formed by uniformly dispersing nano silver particles having particle size of 20-40 nm in graphene layer having thickness of 0.8-1 nm. The graphite/silver particle composite membrane comprises 33.55-60.26 wt.% silver and 39.74-66.45 wt.% graphene. USE - Graphene/silver particle composite nanofiltration membrane used in preparing water flux or filtration performance apparatus. ADVANTAGE - The product has good water flux and filtering performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of graphene/silver particle composite nanofiltration membrane comprising ultrasonically dispersing 1 mg/mL graphene oxide aqueous solution to uniform, dripping 20 mg/mL silver nitrate aqueous solution, adding polyvinylpyrrolidone solution with molecular weight of 24000 to 1-2 wt.%, ultrasonically dispersing to uniform, transferring into three-mouth flask, adding sodium citrate aqueous solution, heating to 100 degrees C, slowly adding sodium borohydride water solution, reacting for 8-9 hours, continuously magnetic stirring, cooling, taking different amounts of graphene-silver particle composite solution, vacuum filtering, and naturally drying. The ratio of graphene oxide and silver nitrate is 1:1-3. The mass ratio of sodium citrate and silver nitrate is 5.5-8.25:1. The mass ratio of sodium borohydride to graphene oxide is 2.5-5:1.