• 专利标题:   Preparation of flame retardant anti-molten polyester material involves modifying graphene with silane coupling agent, adding ethylene glycol, dispersing, and adding terephthalic acid, hexakis(4-nitrophenoxy) cyclotriphosphazene and catalyst.
  • 专利号:   CN107245228-A, CN107245228-B
  • 发明人:   WEI K
  • 专利权人:   WEI K, SHENZHEN GK PLASTICS CO LTD
  • 国际专利分类:   C08G063/183, C08G063/86, C08K013/06, C08K003/04, C08K005/103, C08K005/134, C08K005/5399, C08K009/06, C08L027/18, C08L067/02, C08L083/07
  • 专利详细信息:   CN107245228-A 13 Oct 2017 C08L-067/02 201782 Pages: 8 Chinese
  • 申请详细信息:   CN107245228-A CN10479884 22 Jun 2017
  • 优先权号:   CN10479884

▎ 摘  要

NOVELTY - Preparation of flame retardant anti-molten polyester material involves modifying graphene with silane coupling agent to obtain modified graphene; and adding modified graphene into ethylene glycol, performing ultrasonic dispersion, adding terephthalic acid, hexakis(4-nitrophenoxy) cyclotriphosphazene containing 0.15-0.25 wt.% copolymerized polyethylene terephthalate and catalyst ethylene glycol antimony, heating, and when the reaction water reaches more than 90% of theoretical value performing polycondensation reaction at 275-285 degrees C to obtain modified phosphorus-containing copolymerized PET. USE - Method for preparing flame retardant anti-molten polyester material (claimed). ADVANTAGE - The product is safe and reliable, and has limit oxygen index of more than 33%, and good flame-retardant effect. DETAILED DESCRIPTION - Preparation of flame retardant anti-drop polyester material comprises modifying graphene with silane coupling agent to obtain modified graphene; adding modified graphene into ethylene glycol, performing ultrasonic dispersion, adding terephthalic acid, hexakis(4-nitrophenoxy) cyclotriphosphazene containing 0.15-0.25 wt.% copolymerized polyethylene terephthalate and catalyst ethylene glycol antimony, heating at 230-260 degrees C for esterification reaction, and when the reaction water reaches more than 90% of theoretical value performing polycondensation reaction at 275-285 degrees C to obtain modified phosphorus-containing copolymerized PET; and mixing modified graphene, modified phosphorus-containing copolymerized PET and polyvinyl silsesquioxane, and PTFE at 100:0.4-1.0:0.4-0.8 mass ratio, and melting at 260-270 degrees C.