• 专利标题:   Halogen-free low-dielectric epoxy resin composition useful in laminated plate and printed circuit board, comprises e.g. dicyclopentadiene epoxy resin, cresol novolac epoxy resin, maleimide resin, and 9,10-dihydro-9-oxa-10-phosphaphenan-threne-10-oxide-bisphenol phenolic resin hardener.
  • 专利号:   CN114573946-A
  • 发明人:   CHEN K, YU D
  • 专利权人:   ITEQ WUXI ELECTRONICS TECHNOLOGY CORP
  • 国际专利分类:   B32B015/092, B32B027/04, C08K013/04, C08K003/36, C08K005/3492, C08K007/14, C08K007/18, C08L063/00, C08L063/04, C08L079/04, C08L079/08, H05K001/03
  • 专利详细信息:   CN114573946-A 03 Jun 2022 C08L-063/00 202286 Chinese
  • 申请详细信息:   CN114573946-A CN11385802 01 Dec 2020
  • 优先权号:   CN11385802

▎ 摘  要

NOVELTY - Halogen-free low-dielectric epoxy resin composition comprises 5-15 pts. wt. dicyclopentadiene epoxy resin, 25-35 pts. wt. cresol novolac epoxy resin, 55-65 pts. wt. maleimide resin, 20-30 pts. wt. 9,10-dihydro-9-oxa-10-phosphaphenan-threne-10-oxide (DOPO)-bisphenol phenolic resin hardener, 65-75 pts. wt. cyanate resin, 5-15 pts. wt. crosslinking agent, 35-45 pts. wt. non-DOPO flame retardant, and 1-5 pts. wt. toughening agent, where the toughening agent is a core-shell polymer comprising an intermediate layer containing 30-100 wt.% multifunctional monomers and 0-70 wt.% vinyl monomers, and the shell part of the core-shell polymer comprises epoxy monomers. USE - The halogen-free low-dielectric epoxy resin composition is useful in laminated plate and printed circuit board e.g. high-frequency printed circuit boards. ADVANTAGE - The halogen-free low-dielectric epoxy resin composition has good thermal resistance and toughness, and has low dielectric index. The laminated plate formed using the composition has improved has good thermal resistance and toughness. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: laminated board, comprising a resin substrate provided with multiple prepreg films, each of the prepreg films is composed of a glass fiber cloth by coating the halogen-free and low-dielectric epoxy resin composition, and a metal foil layer disposed on at least one surface of the resin substrate; and printed circuit board.