• 专利标题:   Preparing super hydrophobic graphene aerogel comprises e.g. dispersing graphene oxide in deionized water, ultrasonic dispersing, adding dopamine and reducing agent into ascorbic acid in graphene solution and stirring.
  • 专利号:   CN106744912-A
  • 发明人:   HU M, MA P, YANG S
  • 专利权人:   CHINESE ACAD SCI GUANGZHOU CHEM RES INST, XINJIANG TECH INST PHYSICS CHEM CH, CHINESE ACAD SCI HOLDINGS CO LTD
  • 国际专利分类:   B01J020/20, B01J020/28, B01J020/30, C01B032/198
  • 专利详细信息:   CN106744912-A 31 May 2017 C01B-032/198 201747 Pages: 7 Chinese
  • 申请详细信息:   CN106744912-A CN10140257 10 Mar 2017
  • 优先权号:   CN10140257

▎ 摘  要

NOVELTY - Preparing super hydrophobic graphene aerogel comprises e.g. dispersing graphene oxide in deionized water, ultrasonic dispersing to obtain graphene oxide solution, adding dopamine and reducing agent to ascorbic acid in graphene solution, stirring under magnetic force and pouring into container and sealing, heating in oven to obtain graphene hydrogel, subjecting graphene hydrogel to soaking with deionized water, washing and performing freeze-washing to obtain frozen sample and then freeze-drying, placing freeze-dried sample in a closed vessel and then concentrating. USE - The method is useful for preparing super hydrophobic graphene aerogels (claimed). ADVANTAGE - The graphene aerogels has simple process, efficient, excellent mechanical properties, good thermal stability, high oil absorption rate and cycle stability, and product is environmentally friendly. DETAILED DESCRIPTION - Preparing super hydrophobic graphene aerogel comprises (i) dispersing graphene oxide in deionized water, ultrasonic dispersing to obtain uniform concentration of 2-8 mg/ml graphene oxide solution, (ii) adding 0-1.5 mg/ml dopamine and reducing agent to 1-16 mg/ml ascorbic acid in obtained graphene solution in step (i), stirring under magnetic force and pouring into container and sealing, heating in oven at 60-100 degrees C and insulating for 2-12 hours to obtain graphene hydrogel, (iii) subjecting graphene hydrogel obtained in step (ii) to soaking with deionized water, washing and performing freeze-washing at -196 degrees C to obtain frozen sample and then freeze-drying to obtain a freeze-dried sample, and (iv) placing freeze-dried sample obtained in step (iii) in a closed vessel containing long carbon alkoxysilane or fluorinated long carbon alkoxysilane material-ethanol solution at concentration of 1-5 wt% at 50-80 degrees C for 3-24 hours and then to obtain final product.