• 专利标题:   Agent used for coating glass, comprises titanium dioxide, platinum, silica, carnauba wax or ladder-type silsesquioxane polymer resin, ethanol, water, and graphene solution formed using graphite, potassium persulfate and phosphorus pentoxide.
  • 专利号:   KR1894453-B1
  • 发明人:   BONG S P
  • 专利权人:   PARK B S
  • 国际专利分类:   C03C017/23, C03C017/28, C09D191/06, C09D005/16, C09D007/40
  • 专利详细信息:   KR1894453-B1 04 Sep 2018 C09D-005/16 201863 Pages: 11
  • 申请详细信息:   KR1894453-B1 KR091874 20 Jul 2017
  • 优先权号:   KR091874

▎ 摘  要

NOVELTY - A coating agent comprises 0.01-1 wt.% graphene solution, 0.1-5 wt.% titanium dioxide, 0.01-0.9 wt.% platinum, 1-30 wt.% silica, 30-50 wt.% carnauba wax or 5-30 wt.% ladder-type silsesquioxane polymer resin (I), 1-30 wt.% ethanol, and 1-10 wt.% or 1-20 wt.% water. The graphene solution is obtained by mixing 10 g potassium persulfate, 10 g phosphorus pentoxide and 50 ml sulfuric acid, heating to 90 degrees C in hot water bath, cooling to 80 degrees C, adding 12 g graphite, reacting for 4-5 hours, diluting the mixture with 2 L distilled water, stirring for 12 hours, filtering the diluted solution using 0.2 mu m-nylon filter, pretreating the graphite particles with 460 mL sulfuric acid, adding 60 g potassium permanganate, stirring at 35 degrees C for 2 hours, adding 20-30 mL distilled water, maintaining at 40-50 degrees C, adding hydrochloric acid and distilled water in ratio of 1:2, stirring, adding 2.8 L distilled water, diluting, stirring for 3 hours, adding hydrogen peroxide, and stirring at pH of 5-7. USE - Agent is used for coating glass (claimed). ADVANTAGE - The coating agent has excellent removal effect with respect to volatile organic compound from room, durability, antifouling property, transparency, adhesiveness with respect to house dust which is a cause of pollen allergy, atopic dermatitis and asthma. DETAILED DESCRIPTION - A coating agent comprises 0.01-1 wt.% graphene solution, 0.1-5 wt.% titanium dioxide, 0.01-0.9 wt.% platinum, 1-30 wt.% silica, 30-50 wt.% carnauba wax or 5-30 wt.% ladder-type silsesquioxane polymer resin of formula (I), 1-30 wt.% ethanol, and 1-10 wt.% or 1-20 wt.% water. The graphene solution is obtained by mixing 10 g potassium persulfate, 10 g phosphorus pentoxide and 50 ml sulfuric acid, heating to 90 degrees C in hot water bath, cooling to 80 degrees C, adding 12 g graphite, reacting for 4-5 hours, diluting the mixture with 2 L distilled water, stirring for 12 hours, filtering the diluted solution using 0.2 mu m-nylon filter, pretreating the graphite particles with 460 mL sulfuric acid, adding 60 g potassium permanganate, stirring at 35 degrees C for 2 hours, adding 20-30 mL distilled water, maintaining at 40-50 degrees C, adding hydrochloric acid and distilled water in ratio of 1:2, stirring, adding 2.8 L distilled water, diluting, stirring for 3 hours, adding hydrogen peroxide, and stirring at pH of 5-7. R1 = H, halo, amino, (meth)acryl, phenyl, 1-10C alkyl, 2-10C alkenyl, 6-40C aryl, or 3-40C heteroaryl; R11 = epoxy, (meth)acryl, isocyanato, phenyl, 1-10C alkyl, 2-20C alkenyl, 1-10C alkoxy, 6-40C aryl, or 3-40C heteroaryl;and n = 2-200.