• 专利标题:   New lithium-ion battery binder i.e. substituted 2-(hydroxymethyl)-5-(lithiooxy)-4-methyl-5-oxopentanoic acid useful for lithium battery pole piece, prepared by e.g. copolymerizing water-soluble polymer containing hydroxy group with acrylic acid monomer, and then reacting.
  • 专利号:   CN115746207-A
  • 发明人:   XUE X
  • 专利权人:   YUANLI SHANGHAI NEW MATERIAL TECHNOLOGY CO LTD
  • 国际专利分类:   C08F220/06, C08F220/18, C08F230/08, C08F251/00, C08F251/02, C08F261/04, H01M010/0525, H01M010/42, H01M004/13, H01M004/62
  • 专利详细信息:   CN115746207-A 07 Mar 2023 C08F-251/02 202326 Chinese
  • 申请详细信息:   CN115746207-A CN11480843 24 Nov 2022
  • 优先权号:   CN11480843

▎ 摘  要

NOVELTY - Lithium-ion battery binder i.e. substituted 2-(hydroxymethyl)-5-(lithiooxy)-4-methyl-5-oxopentanoic acid (I) is new. USE - (I) is useful for lithium battery pole piece (claimed). ADVANTAGE - (I): can reduce the intrinsic lithium ion diffusion resistance of the binder by modifying the water-soluble polymer, introducing acrylic acid and other unsaturated olefin monomers; improves the power performance of lithium-ion batteries at low temperatures and reducing internal resistance; improves the lithiation efficiency of the carboxy group in acrylic acid on the one hand, and on the other hand, some polar groups in the side chain can also self-crosslink or react with the surface of the active material to form a reliable bond the network; inhibits the expansion of the pole piece, ensures the stability, and improves the cycle life of the battery. DETAILED DESCRIPTION - Lithium-ion battery binder i.e. substituted 2-(hydroxymethyl)-5-(lithiooxy)-4-methyl-5-oxopentanoic acid of formula (I) is new. M group = repeating structural unit of water-soluble polymer containing a hydroxy group, number of repeating structural unit modified by the hydroxy group is p, and number of repeating structural unit with unmodified hydroxy group is k; a and b = number of repeating units of acrylic acid (including methacrylate, lithium acrylate, sodium acrylate, potassium acrylate, lithium methacrylate, sodium methacrylate and potassium methacrylate) and acrylate lithium in the copolymer composition; c1, c2...cm = number of repeating units of unsaturated olefin monomer (including vinyl silane monomer (including vinyltrimethoxysilane, vinyltriethoxysilane, vinyl tri-tert-butylperoxysilane, vinyltris(2-methoxyethoxy)silane, vinyltriisopropoxysilane, vinyltris(trimethylsiloxy)silane, vinyltris(triethylsiloxy)silane, vinyltris(dimethylsiloxy)silane, γ-methacryloxypropyltrimethoxysilane or γ-methacryloxypropyltris(β-trimethoxyethoxysilane)), acrylate, acrylamide, acrylonitrile, vinyl acetate, vinyl carbonate, fluorinated ethylene carbonate or propylene carbonate) other than acrylic acid monomer; m = number of types of unsaturated olefin monomer other than acrylic acid monomer, 1-3; p, k, m, a, b, c1, c2...cm= 0-100000000; p, b and m = not 0; and R1-R8...R4m-1-R4m-4= H, phenyl, hydroxy, carboxy, amino, cyano, amido, -SO3Na, 1-methylpyrrolidin-2-one, methyl formate compound of formula (II), acetic acid compound of formula (III), methyl formate compound of formula (IV), acetamide compound of formula (V), acetic acid compound of formula (VI), N-methylformamide compound of formula (VII), methylbenzene compound of formula (VIII), siloxy, or 1-8C straight-chain or branched-chain alkyl. INDEPENDENT CLAIMS are also included for: Preparation of (I); and Lithium battery pole piece comprising electrode active material, thickening agent, conductive agent, emulsion and lithium ion battery binder, where lithium battery pole piece is a positive pole piece or a negative pole piece.