• 专利标题:   Preparing 3D printing battery electrode comprises designing printing model, and introducing printing model into the 3 D printer, setting the printing parameter, adding printing slurry into 3 D printer for printing, carrying out photo-curing reaction, hydrothermal reaction in hydrothermal medium.
  • 专利号:   CN114103115-A, CN114103115-B
  • 发明人:   CHEN G, WANG C, ZHU Q, LIU K, ZHANG P
  • 专利权人:   HARBIN INST TECHNOLOGY AT WEIHAI
  • 国际专利分类:   B29C035/04, B29C035/08, B29C064/307, B33Y040/20, B33Y080/00, H01M004/02, H01M004/1395, H01M004/62
  • 专利详细信息:   CN114103115-A 01 Mar 2022 B29C-064/307 202273 Chinese
  • 申请详细信息:   CN114103115-A CN11158716 30 Sep 2021
  • 优先权号:   CN11158716

▎ 摘  要

NOVELTY - Preparing 3D printing battery electrode comprises (i) designing the printing model according to the size of the device, and introducing the printing model into the 3 D printer, setting the printing parameter, (ii) adding the printing slurry into the 3 D printer for printing to obtain battery electrode, where the printing slurry is mainly prepared from electrode active material, conductive agent, binder and photopolymerization agent prepared in proportion, (iii) adding battery electrode obtained in step (ii) under an ultraviolet lamp for photocuring reaction for 10-40 minutes, and drying at room temperature, (iv) adding battery electrode obtained in step (iii) into hydrothermal reactor to carry out hydrothermal reaction in hydrothermal medium i.e. graphene oxide solution (v) drying the battery electrode obtained in step (iv) and performing vacuum sintering at 420-600℃ for 1-3 hours and (vi) drying the battery electrode obtained in step (v) to obtain final product. USE - The method is useful for preparing 3D printing battery electrode. ADVANTAGE - The method: solves problem by preventing rupture of the SEI film and inhibiting growth of lithium dendrites compared to existing battery electrodes in market. DETAILED DESCRIPTION - Preparing 3D printing battery electrode comprises (i) designing the printing model according to the size of the device, and introducing the printing model into the 3 D printer, setting the printing parameter, (ii) adding the printing slurry into the 3 D printer for printing to obtain battery electrode, where the printing slurry is mainly prepared from electrode active material, conductive agent, binder and photopolymerization agent prepared in proportion, (iii) adding battery electrode obtained in step (ii) under an ultraviolet lamp for photocuring reaction for 10-40 minutes, and drying at room temperature for 2-4 hours, (iv) adding battery electrode obtained in step (iii) into hydrothermal reactor to carry out hydrothermal reaction in hydrothermal medium i.e. graphene oxide solution (with a concentration of 0.01-2 mg/ml) at 120-240℃ for 2-6 hours, (v) drying the battery electrode obtained in step (iv) and performing vacuum sintering at 420-600℃ for 1-3 hours and (vi) drying the battery electrode obtained in step (v) to obtain final product.