• 专利标题:   Method for preparing porous silicon/graphene composite material that is utilized in lithium ion battery, involves selecting rice husk, washing and drying to remove alkali metal oxide impurities, followed by adding metal oxide mixture.
  • 专利号:   CN104009235-A, CN104009235-B
  • 发明人:   ZHAO S, LIU S
  • 专利权人:   UNIV KUNMING SCI TECHNOLOGY
  • 国际专利分类:   H01M004/36, H01M004/583
  • 专利详细信息:   CN104009235-A 27 Aug 2014 H01M-004/583 201477 Pages: 10 Chinese
  • 申请详细信息:   CN104009235-A CN10201535 13 May 2014
  • 优先权号:   CN10201535

▎ 摘  要

NOVELTY - A porous silicon/graphene composite material preparing method involves selecting rice husk, washing, filtering and drying the rice hush to remove alkali metal oxide impurities through pyrolysis. The precursor salt solution is added to husk under catalytic carbonizing reaction to obtain carbonized product. The carbonized product is subjected to aerobic oxidation condition to obtain oxidation product, followed by adding metal oxide mixture with oxidation product to obtain reduction product, washing the reduction product with water and drying to obtain finished product. USE - Method for preparing porous silicon/graphene composite material that is utilized in lithium ion battery. ADVANTAGE - The method enables preparing composite material with high density capacity, high efficiency and good circulation property. DETAILED DESCRIPTION - A porous silicon/graphene composite material preparing method involves selecting rice husk, washing, filtering and drying the rice hush to remove alkali metal oxide impurities through pyrolysis under absence of oxygen or low oxygen condition. The obtained rice husk after pyrolysis process is according to liquid-solid ratio of 20-80:1 ml/g. The precursor salt solution is added to husk at 700-1000 degrees C for 1-5 hours under high temperature catalytic carbonizing reaction to obtain carbonized product. The carbonized product is subjected to aerobic low temperature oxidation condition at 300-600 degrees C for 0.1-4 hours to obtain oxidation product, followed by adding metal oxide mixture with oxidation product under low oxygen condition to obtain reduction product, washing the reduction product with water and drying to obtain a porous silicon/graphene composite material, where the precursor salt solution is a transition metal salt, the solvent is water, ethanol or acetone.