• 专利标题:   Preparing few-layer graphitized carbon-coated cobalt-platinum nanoparticles electrocatalyst, comprises e.g. reacting carbon carrier and oleylamine and octadecene, cobalt and platinum acetylacetonate, borane-t-butylamine, and calcining organic molecular ligand-modified cobalt-platinum nanoparticles.
  • 专利号:   CN115763854-A
  • 发明人:   YANG D, LI T, FAN P, CAO Y, DONG A
  • 专利权人:   UNIV FUDAN
  • 国际专利分类:   H01M004/86, H01M004/88, H01M004/92
  • 专利详细信息:   CN115763854-A 07 Mar 2023 H01M-004/92 202326 Chinese
  • 申请详细信息:   CN115763854-A CN11524634 01 Dec 2022
  • 优先权号:   CN11524634

▎ 摘  要

NOVELTY - Preparing few-layer graphitized carbon-coated cobalt-platinum nanoparticles electrocatalyst, comprises e.g. (i) adding certain amount of carbon carrier and organic solvent into the three-necked flask, where organic solvent is oleylamine and octadecene, dispersing carbon carrier, (ii) taking cobalt acetylacetonate and platinum acetylacetonate as metal precursor, and borane-t-butylamine as reducing agent, (iii) adding product of step (ii) at room temperature, adding n-hexane, ethanol and isopropanol into reaction product, centrifuging and washing many times to obtain cobalt-platinum nanoparticle precursor loaded wrinkled porous graphene, modifying surface with certain density of organic molecular ligands, and placing in an oven to dry, and (iv) subjecting organic molecular ligand-modified cobalt-platinum nanoparticles to suitable high-temperature calcination treatment, converting organic molecular ligands on the surface of the particles into uniform few-layer graphitized carbon. USE - The electrocatalyst is useful in electrocatalysis, proton exchange membrane fuel cells and many other aspects. ADVANTAGE - The method is simple and can be prepared on a large scale; utilizes easy to obtain raw materials; and has low production cost.