• 专利标题:   Preparing titanium dioxide-graphene negative electrode material involves adding tetrabutyl titanate to anhydrous ethanol, and then adding graphene aqueous solution, and uniformly stirring at normal temperature, and mixing absolute ethanol.
  • 专利号:   CN108807923-A
  • 发明人:   TANG Y, XIONG X, YANG X, ZHENG S, FU H
  • 专利权人:   QINGYUAN JIAZHI NEW MATERIALS RES INST
  • 国际专利分类:   H01M004/36, H01M004/48, H01M004/583, H01M010/054, B82Y030/00
  • 专利详细信息:   CN108807923-A 13 Nov 2018 H01M-004/36 201901 Pages: 11 Chinese
  • 申请详细信息:   CN108807923-A CN10645248 21 Jun 2018
  • 优先权号:   CN10645248

▎ 摘  要

NOVELTY - Preparing titanium dioxide-graphene negative electrode material involves adding tetrabutyl titanate to anhydrous ethanol, and then adding a graphene aqueous solution, and uniformly stirring at normal temperature. The amount of absolute ethanol is mixed with 50-5000 milliliter anhydrous ethanol per gram of tetrabutyl titanate. The amount of the aqueous graphene solution added is 0.5-300 milliliter per gram of tetrabutyl titanate, and the concentration of the graphene aqueous solution is 1-10 milligram per milliliter. The mixture is centrifuged, and the obtained precipitate is freeze-dried to obtain a composite nanosheet of titanium dioxide/graphene after drying. The obtained titanium dioxide/graphene composite nanosheet is subjected to high temperature phosphating treatment in a phosphorus-containing atmosphere to obtain a phosphorus-doped titanium oxide/graphene composite nanosheet. USE - Method for preparing titanium dioxide-graphene negative electrode material. ADVANTAGE - The method enables to preparing titanium dioxide-graphene negative electrode material whcih is helps to improves conductivity of composite electrode material, improves sodium ion transport capacity of titanium dioxide surface and improves sodium storage performance of titanium dioxide/graphene composite electrode.