• 专利标题:   Preparation of vanadium tetrasulfide/graphene composite material for e.g. lithium-ion battery by adding sulfur source and graphene oxide to vanadium-containing leaching solution, stirring, heating, separating, washing precipitate and drying.
  • 专利号:   CN110247050-A
  • 发明人:   JIANG T, WEN J, CAO J, CHEN B, LI L
  • 专利权人:   UNIV NORTHEASTERN
  • 国际专利分类:   H01M004/58, H01M004/62
  • 专利详细信息:   CN110247050-A 17 Sep 2019 H01M-004/58 201988 Pages: 9 Chinese
  • 申请详细信息:   CN110247050-A CN10540706 21 Jun 2019
  • 优先权号:   CN10540706

▎ 摘  要

NOVELTY - Preparing a vanadium tetrasulfide/graphene composite material using a vanadium-containing leaching solution involves: (S1) mixing a vanadium-containing mineral with a calcining additive to obtain a mixed material, calcining or roasting the vanadium-containing mineral without salt to obtain a calcined clinker; (S2) leaching the calcined clinker in a leaching medium, and then carrying out solid-liquid separation to obtain a vanadium-containing leaching solution and tailings; (S3) adding a sulfur source and graphene oxide to the vanadium-containing leaching solution, stirring to dissolve the sulfur source, and uniformly dispersing the graphene oxide to obtain a mixed liquid; (S4) transferring the mixed liquid obtained in the step (S3) to the reaction vessel, heating, reacting, and cooling after the reaction is completed; and (S5) subjecting the obtained product to solid-liquid separation, repeatedly washing the precipitate and drying. USE - The method is useful for preparing a vanadium tetrasulfide/graphene composite material, using a vanadium-containing leaching solution, for sodium-ion battery or lithium-ion battery. ADVANTAGE - The method shortens the preparation flow of the composite material, and greatly reduces the production cost.