• 专利标题:   Two-dimensional/two-dimensional self-assembly of protonic niobate complex/reduced graphene oxide composite material, comprises e.g. taking composite material as a cathode, lithium metal as a reference electrode, and assembly.
  • 专利号:   CN107895787-A
  • 发明人:   XIONG J, FAN J
  • 专利权人:   UNIV LONGYAN
  • 国际专利分类:   H01M004/36, H01M004/48, H01M004/66, H01M010/0525
  • 专利详细信息:   CN107895787-A 10 Apr 2018 H01M-004/36 201835 Pages: 7 Chinese
  • 申请详细信息:   CN107895787-A CN11146484 17 Nov 2017
  • 优先权号:   CN11146484

▎ 摘  要

NOVELTY - Two-dimensional/two-dimensional self-assembly of protonic niobate complex (HNb3O8)/reduced graphene oxide composite material for lithium ion battery, comprises e.g. mixed grinding protonic niobate complex/reduced graphene oxide composite material with polyvinylidene fluoride and acetylene black, coating uniformly on a copper foil, drying and taking as a cathode, taking lithium metal as a reference electrode and a counter electrode, then taking lithium perchlorate/ethylene carbonate-dimethyl carbonate solution as electrolyte in a glove box, and assembly into lithium ion battery. USE - Used as two-dimensional/two-dimensional self-assembly of protonic niobate complex/reduced graphene oxide composite material for lithium ion battery. ADVANTAGE - The method: is simple; consumes low energy; has low cost, excellent repeatability, and high specific capacity, high cycle stability and excellent multiplying power discharge performance of lithium ion battery. DETAILED DESCRIPTION - Two-dimensional/two-dimensional self-assembly of protonic niobate complex (HNb3O8)/reduced graphene oxide composite material for lithium ion battery, comprises mixed grinding protonic niobate complex/reduced graphene oxide composite material with polyvinylidene fluoride and acetylene black, coating uniformly on a copper foil, drying and taking as a cathode, taking lithium metal as a reference electrode and a counter electrode, then taking lithium perchlorate/ethylene carbonate-dimethyl carbonate solution as electrolyte in a glove box, and assembly into lithium ion battery, where the composite material prepared by taking organic amine tetrabutylammonium hydroxide intercalation protonic niobate complex, stripped prepared niobate (Nb3O8-(tetrabutylammonium cation (TBA(+)) nano sheet colloid suspension and graphene oxide nano-sheet sol prepared by classical Hummer method as main raw material, then mixing with graphene oxide, and stirring uniformly to obtain mixed solution, then adjusting pH using hydrochloric acid, and carrying out one-step hydrothermal reaction.