• 专利标题:   Directly growing graphene thin porous separation membrane comprises coating a mixture of etching agent, high molecular polymer and solvent-A on a metal foil, calcining at high temperature under the oxygen-free condition.
  • 专利号:   CN107051228-A, WO2018218644-A1, US2019176094-A1
  • 发明人:   QUAN X, WEI G, CHEN S, YU H
  • 专利权人:   UNIV DALIAN TECHNOLOGY, UNIV DALIAN TECHNOLOGY
  • 国际专利分类:   B01D067/00, B01D071/02, C01B032/184, B01D069/12
  • 专利详细信息:   CN107051228-A 18 Aug 2017 B01D-071/02 201766 Pages: 8 Chinese
  • 申请详细信息:   CN107051228-A CN10404233 02 Jun 2017
  • 优先权号:   CN10404233, WOCN086957, US16325168

▎ 摘  要

NOVELTY - Directly growing graphene thin porous separation membrane comprises: (i) coating a mixture of etching agent, high molecular polymer and solvent-A on a metal foil, calcining at high temperature under the oxygen-free condition, or coating a solution-B or dispersion-B of etching agent on the metal foil, then covering a layer of organic high molecular polymer film, calcining at 400-1200 degrees C for 10 minutes to 4 hours under oxygen-free condition; and (ii) removing the metal foil and reaction product to obtain ultra-thin porous graphene separating membrane. USE - The method is useful for directly growing graphene thin porous separation membrane (claimed). ADVANTAGE - The method is simple, economical, and does not require expensive devices. DETAILED DESCRIPTION - Directly growing graphene thin porous separation membrane comprises: (i) coating a mixture of etching agent, high molecular polymer and solvent-A (mass ratio of 1:0.5-50:100-1000) on a metal foil, calcining at high temperature under the oxygen-free condition, or coating a solution-B or dispersion-B of etching agent on the metal foil, then covering a layer of organic high molecular polymer film, calcining at high temperature under oxygen-free condition, where the mass ratio of etching agent, organic high molecular polymer and solvent-B is 1:0.5-50:100-1000; where calcinations is carried out at 400-1200 degrees C for 10 minutes to 4 hours; and (ii) removing the metal foil and reaction product to obtain ultra-thin porous graphene separating membrane, which is a single layer, double-layer or multilayer.