• 专利标题:   Manganese oxide/carbon nanotube/graphene anode composite material is produced by dispersing carbon nanotubes in permanganate aqueous solution, refluxing, then mixing with polycationic electrolyte aqueous solution, dispersing, and calcining.
  • 专利号:   CN109037608-A
  • 发明人:   TONG H, WANG X, YU R, YAO Y, ZHANG B, YU W, ZHENG J
  • 专利权人:   UNIV CENT SOUTH
  • 国际专利分类:   H01M004/36, H01M004/50, H01M004/62, H01M010/0525, B82Y030/00
  • 专利详细信息:   CN109037608-A 18 Dec 2018 H01M-004/36 201920 Pages: 9 Chinese
  • 申请详细信息:   CN109037608-A CN10690868 28 Jun 2018
  • 优先权号:   CN10690868

▎ 摘  要

NOVELTY - A manganese oxide/carbon nanotube/graphene anode composite material is produced by: (1) dispersing carbon nanotubes in a permanganate aqueous solution, performing a reflux reaction, naturally cooling, filtering, washing, and drying to obtain a manganese/carbon nanotube precursor; (2) mixing the manganese/carbon nanotube precursor obtained in the step (1) and a polycationic electrolyte aqueous solution, stirring, filtering and drying to obtain a modified manganese/carbon nanotube precursor; (3) dispersing the modified manganese/carbon nanotube precursor obtained in the step (2) in water, then mixing with an aqueous solution of graphene oxide, stirring, filtering and drying to obtain a precursor/graphene mixture; and (4) calcining the precursor/graphene mixture obtained in the step (3) in a protective atmosphere, and cooling to room temperature along with a furnace. USE - Manganese oxide/carbon nanotube/graphene anode composite material. ADVANTAGE - The manganese oxide/carbon nanotube/graphene anode composite material can be simply and industrially produced in an environmentally-friendly manner, and has high electronic conductivity and ionic conductivity, short ion diffusion channel and excellent rate performance.