• 专利标题:   Preparation of graphene-barium ferromagnetic composite material used as material as filler of electromagnetic shielding coating, injecting dissolved mixture of ferric chloride and barium chloride to graphene dispersion and washing solid.
  • 专利号:   CN107195417-A
  • 发明人:   GAN Z, WANG J, XU C, ZHENG Q
  • 专利权人:   XIAMEN BADOU NEW MATERIALS TECHNOLOGY CO LTD
  • 国际专利分类:   H01F001/42
  • 专利详细信息:   CN107195417-A 22 Sep 2017 H01F-001/42 201776 Pages: 8 Chinese
  • 申请详细信息:   CN107195417-A CN10554108 10 Jul 2017
  • 优先权号:   CN10554108

▎ 摘  要

NOVELTY - Deionized water is added to surfactant and agitated. Graphene is added to mixture and dispersed, to obtain graphene dispersion. Graphene dispersion is placed in oil bath pot of three-necked flask. Ferric chloride hexahydrate, ferrous chloride tetrahydrate and barium chloride dihydrate are dissolved in deionized water, and injected to graphene dispersion and heated. Sodium hydroxide and ammonium carbonate aqueous solution are injected to mixture, reacted, cooled and magnet adsorbed. The solid is washed and freeze-dried, to obtain graphene-barium ferromagnetic composite material. USE - Preparation of graphene-barium ferromagnetic composite material used as material as filler of electromagnetic shielding coating. ADVANTAGE - The method enables preparation of graphene-barium ferromagnetic composite material with high yield within short period of time under mild reaction condition. DETAILED DESCRIPTION - Deionized water is added to surfactant and mechanically agitated. Graphene is added to mixture and ultrasonically dispersed for 20-30 minutes, to obtain graphene dispersion. Graphene dispersion is placed in oil bath pot of three-necked flask. Condensing pipe water is condensed and inert gas is introduced. Ferric chloride hexahydrate, ferrous chloride tetrahydrate and barium chloride dihydrate are dissolved in deionized water, and injected to graphene dispersion and heated at 60-70 degrees C. Sodium hydroxide and ammonium carbonate aqueous solution are injected to mixture, reacted at 60-70 degrees C for 0.5-1 hour, cooled to room temperature and magnet adsorbed to remove supernatant. The solid is washed with deionized water and freeze-dried, to obtain graphene-barium ferromagnetic composite material.