• 专利标题:   Catalyst used for electrode for e.g. carbon-dioxide electrolytic reduction reaction, contains nitrogen-containing carbon material comprising iron atom which has iron-nitrogen structure in which each of nitrogen atoms is coordinated, having preset active point density.
  • 专利号:   JP2021115501-A
  • 发明人:   KOJIMA R, KAWASHIMA S, SHIOZAKI E, NAKAI S
  • 专利权人:   ASAHI KASEI CORP
  • 国际专利分类:   B01J031/02, B01J031/22, B01J037/08
  • 专利详细信息:   JP2021115501-A 10 Aug 2021 B01J-031/22 202169 Pages: 25 Japanese
  • 申请详细信息:   JP2021115501-A JP009259 23 Jan 2020
  • 优先权号:   JP009259

▎ 摘  要

NOVELTY - A catalyst comprises a nitrogen-containing carbon material comprising iron atom and a graphene structure containing nitrogen atoms. The iron atom has an iron-nitrogen structure in which each of four nitrogen atoms is coordinated. The iron-nitrogen structure has an active point density of 3x 10-5-1x 10-4 mol sites/g. USE - Catalyst is used for electrode (claimed) for carbon-dioxide electrolytic reduction reaction for producing carbon monoxide used as raw material of chemical product and nitrogen electrolytic reduction reaction for producing ammonia used as fertilizer. ADVANTAGE - The catalyst has high carbon dioxide reduction activity and nitrogen reduction activity. DETAILED DESCRIPTION - A catalyst comprises a nitrogen-containing carbon material comprising iron atom and a graphene structure containing nitrogen atoms. The iron atom has an iron-nitrogen (Fe-N4) structure in which each of four nitrogen atoms is coordinated. The iron-nitrogen structure has an active point density of 3x 10-5-1x 10-4 mol sites/g. An INDEPENDENT CLAIM is included for manufacture of the catalyst, which involves heat-treating a precursor containing a zinc phenanthroline complex.