• 专利标题:   Preparation of modified magnetic graphene oxide adsorbent material includes weighing ferric chloride hexahydrate and ethylene glycol, stirring, adding graphene oxide, ammonia and polyvinylpyrrolidone dropwise.
  • 专利号:   CN105289513-A, CN105289513-B
  • 发明人:   GE H, WANG C, TENG C
  • 专利权人:   UNIV JINAN, UNIV JINAN
  • 国际专利分类:   B01J020/22, B01J020/28, B01J020/30, C02F001/28, C02F001/58
  • 专利详细信息:   CN105289513-A 03 Feb 2016 B01J-020/22 201644 Pages: 8 English
  • 申请详细信息:   CN105289513-A CN10858673 01 Dec 2015
  • 优先权号:   CN10858673

▎ 摘  要

NOVELTY - Preparation of modified magnetic graphene oxide adsorbent material includes weighing 1-2 pts. wt. ferric chloride hexahydrate and 0.05 g/mL ethylene glycol, stirring, adding 0.05-0.2 pt. wt. graphene oxide, 1-10 pts. wt. ammonia and 0.05-0.3 pt. wt. polyvinylpyrrolidone dropwise, mixing to obtain homogeneous mixture, placing in PTFE lined autoclave, heating at 160-190 degrees C for 15-24 hours, cooling to room temperature, washing alternately with water and ethanol for three times, freeze-drying and crushing to obtain graphene oxide magnetic material. USE - Method for preparing modified magnetic graphene oxide adsorbent material (claimed). ADVANTAGE - The adsorbent material is environmental-friendly, convenient to perform and has simple preparation and high adsorption capacity. DETAILED DESCRIPTION - Preparation of modified magnetic graphene oxide adsorbent material involves weighing 1-2 pts. wt. ferric chloride hexahydrate and 0.05 g/mL ethylene glycol, stirring, adding 0.05-0.2 pt. wt. graphene oxide, 1-10 pts. wt. ammonia and 0.05-0.3 pt. wt. polyvinylpyrrolidone dropwise, mixing to obtain homogeneous mixture, placing in PTFE lined autoclave, heating at 160-190 degrees C for 15-24 hours, cooling to room temperature, washing alternately with water and ethanol for three times, freeze-drying, crushing to obtain graphene oxide magnetic material, placing 1 pt. wt. silane coupling agent, 2.5-10 pts. wt. absolute ethanol and 5-20 pts. wt. water into three-necked flask, adjusting pH to 4-5, stirring at 300 revolutions/minute (rpm) for 2 hours, adding 1.5-3 pts. wt. graphene oxide magnetic material, stirring at 300 rpm at room temperature for 4 hours, washing with absolute ethanol for three times, freeze-drying, crushing, mixing 0.5-1.5 pts. wt. citric acid powder in solvent, adding 0.5-2 pts. wt. polypeptide, 0.1-1 pt. wt. condensing agent and basic catalyst, stirring at room temperature, adding graphene oxide powder, stirring at 300 rpm for 24 hours, washing alternately with water and ethanol for three times, freeze-drying and crushing.