• 专利标题:   Producing graphene oxide nanoplatelets and derived products, comprises e.g. dosing e.g. a hydrocarbon or mixture of hydrocarbons, placing dosed compounds inside a furnace, and obtaining intermediate material comprising carbon nanofilaments.
  • 专利号:   US2012208022-A1, EP2489632-A1, JP2012167005-A, KR2012094439-A, CN102642826-A, US8641998-B2, EP2489632-B1, ES2540462-T3, CN102642826-B, JP5923796-B2
  • 发明人:   MERINO S C, MARTIN G I, VARELA R H, MERINO A M D P, MERINO SANCHEZ C, MARTIN GULLON I, VARELA RIZO H, MERINO AMAYUELAS M D P, RIZZO H V, SANCHEZ C M, OMARYERAS M D P M, GULLION I M
  • 专利权人:   GRUPO ANTOLIN ING SA, GRUPO ANTOLIN ING SA, GRUPO ANTOLIN ING SA, GRUPO ANTOLIN ING SA, GRUPO ANTOLIN ING SA
  • 国际专利分类:   B32B005/16, B44C001/22, B82Y040/00, C01B031/04, C01B031/02, C23C016/00, C25D015/02, C03C025/68, B82Y030/00
  • 专利详细信息:   US2012208022-A1 16 Aug 2012 B32B-005/16 201257 Pages: 11 English
  • 申请详细信息:   US2012208022-A1 US150928 01 Jun 2011
  • 优先权号:   EP382044

▎ 摘  要

NOVELTY - Producing graphene oxide nanoplatelets and derived products, comprises: (a) dosing of at least a hydrocarbon or mixture of hydrocarbons, a compound of nickel and a compound of sulfur to generate catalytic particles, and a carrier gas; (b) placing the dosed compounds inside a furnace with a working temperature of 900-1500 degrees C; (c) obtaining an intermediate material comprising carbon nanofilaments; (d) heat treatment of the carbon nanofilaments by exposing them to 1500-3000 degrees C; (e) chemical etching; (f) completing the carbon nanofilament cleaving method to obtain graphene oxide nanoplatelets. USE - The method is useful for producing graphene oxide nanoplatelets and derived products. ADVANTAGE - The method provides the graphene oxide nanoplatelets and derived products with: high quality; greater degree of crystallinity; a clearly defined regular and polygonal shape; more stability. DETAILED DESCRIPTION - Producing graphene oxide nanoplatelets and derived products, comprises: (a) dosing of at least a hydrocarbon or mixture of hydrocarbons, a compound of nickel and a compound of sulfur to generate catalytic particles, and a carrier gas; (b) placing the dosed compounds inside a furnace with a working temperature of 900-1500 degrees C, where a chemical vapor deposition method occurs by the floating catalyst method; (c) obtaining an intermediate material comprising carbon nanofilaments, the structure of which comprises a continuous graphite continuous ribbon, where the ribbon comprises a stacking of less than eleven graphene layers spirally rolled around and along the nanofilament main axis; (d) heat treatment of the carbon nanofilaments obtained in step (c) by exposing them to 1500-3000 degrees C in an inert atmosphere to purify, dehydrogenate, defunctionalize and crystallize the nanofilaments to a modified structure in which the number of carbon-carbon bonds is greater than the number of carbon-carbon bonds present in the carbon nanofilaments obtained in step (c); (e) chemical etching comprising a phase of liquid phase oxidation of the treated carbon nanofilaments from step (d), causing their fragmentation, so that starting the cleaving of the graphene layers; (f) completing the carbon nanofilament cleaving method by a physical method to obtain graphene oxide nanoplatelets with polygonal geometry, less than six stacked graphene layers, and a maximum length of 0.1-50 mu m. An INDEPENDENT CLAIM is also included for the graphene oxide nanoplatelets obtained by the method.