• 专利标题:   Method for preparing metal single-atom modified graphene material, which is useful in lithium sulphur battery, involves using carbon dioxide laser to irradiate surface of graphite alkenyl film of load metal complex under air atmosphere.
  • 专利号:   CN115611269-A
  • 发明人:   GUO S, MOU J, HU H, WU M, DONG Z, ZHANG M
  • 专利权人:   UNIV CHINA PETROLEUM EAST CHINA
  • 国际专利分类:   B22F009/30, C01B032/184, C01B032/194, H01M010/052, H01M050/403, H01M050/409, H01M050/431, H01M050/449
  • 专利详细信息:   CN115611269-A 17 Jan 2023 C01B-032/184 202313 Chinese
  • 申请详细信息:   CN115611269-A CN11099327 07 Sep 2022
  • 优先权号:   CN11099327

▎ 摘  要

NOVELTY - The method involves (a) irradiating a carbon source base film under an air atmosphere to obtain a graphene-based film, (b) dropping a dispersion liquid containing a metal complex to a surface of the graphene-type film, and drying to obtain the graphene film loaded with metal complex, where the metal complex is a metal-metal complex with a macrocyclic conjugated structure, and (c) irradiate the surface of graphite alkenyl film of the load metal complex under the air atmosphere using carbon dioxide laser. USE - Method for preparing metal single-atom modified graphene material, which is useful in lithium sulphur battery (all claimed). ADVANTAGE - The metal single-atom modified graphene material is rich in vacancy and topology defect, with three-dimensional fluffy foam structure, and the lattice graphene doped with metal single atom coordination structure, the specific structure can be used as modified material for modification of lithium-sulphur battery membrane. The preparation method has low cost, simple step, fast and high efficiency, universality, and can successfully realize the preparation of metal-single-atom-modified material graphene. DESCRIPTION OF DRAWING(S) - The drawing shows a photo graph view of a metal single-atom modified graphene material.