• 专利标题:   Water-based proton battery electrode based on aza-conjugated porous polymer comprises aza-conjugated porous polymer or hydrated proton storage material, which achieve proton or hydration in proton-containing aqueous electrolyte solution.
  • 专利号:   CN112531162-A, CN112531162-B
  • 发明人:   LIN Z, FAN G, WENG J, HUANG W, HUO F, SHI Z, XI Q
  • 专利权人:   UNIV NORTHWESTERN POLYTECHNICAL
  • 国际专利分类:   H01M010/36, H01M004/60
  • 专利详细信息:   CN112531162-A 19 Mar 2021 H01M-004/60 202134 Pages: 12 Chinese
  • 申请详细信息:   CN112531162-A CN11420026 06 Dec 2020
  • 优先权号:   CN11420026

▎ 摘  要

NOVELTY - Water-based proton battery electrode based on aza-conjugated porous polymer comprises an aza-conjugated porous polymer as a proton or hydrated proton storage material, which achieve proton or hydration in a proton-containing aqueous electrolyte solution electrochemical insertion and extraction of hydrated protons. USE - Water-based proton battery electrode based on aza-conjugated porous polymer. ADVANTAGE - The electrode achieves electrochemical insertion and separation of protons or hydrated protons at highly safe protons-containing aqueous solutions. It utilizes reversible redox-storage proton or hydrated proton of a large number of aromatic aza- sites enriched in the azaconjugated porous polymer. The porous structure of the azaconjugated porous polymer and high specific surface area, not only can realize stable de-embedding of proton with large volume, but also can provide fast ion transport channel and expose more ion storage sites. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a method for preparing an electrode for an aqueous proton battery based on an aza-conjugated porous polymer, which involves grinding and mixing the aza-conjugated porous polymer, conductive agent, binder, and solvent uniformly to form an electrode slurry, where the solvent includes deionized water, dimethyl sulfoxide, N-pyrrolidone, the ratio of organic solvents such as methylformamide, aza-conjugated porous polymer, conductive agent, and binder is 5:4:1-9:0:1, coating the above-mentioned uniformly mixed electrode slurry on the current collector to form a pole piece, placing the above pole piece in a vacuum oven for baking and drying, the drying temperature is 50-150 degrees C, and the drying time is 6-48 hours, the conductive agent includes activated carbon, graphene, Ketjen black, acetylene black, or carbon nanotubes, or a mixture, the binder includes polyvinylidene fluoride, polytetrafluoroethylene, epoxy resin, polyurethane, and sodium carboxymethyl cellulose; and (2) a method for preparing a three-electrode system for testing the aza-conjugated porous polymer-based aqueous proton battery electrode, which involves preparing activated carbon counter electrode pole piece by mixing activated carbon, conductive agent and binder, separating the above-prepared aza-conjugated porous polymer-based water-based proton battery electrode and activated carbon counter electrode pole piece with a separator material, placing into the battery case, and injecting one of the above-mentioned proton-containing water-based electrolyte solutions as electrolyte and inserting the reference electrode.