• 专利标题:   Preparation of nickel-doped void-cobalt oxide-reduced graphene oxide wave absorbent for absorbing electromagnetic waves, involves synthesizing nickel nanowires using nickel chloride hexahydrate, coating with phenolic resin, growing cobalt hydroxide nanosheets, and mixing with graphene suspension.
  • 专利号:   ZA202203072-A
  • 发明人:   MA M, SU X, LIU Y, TONG Z, WAN F, BL Y, CHEN Y, XING Q
  • 专利权人:   UNIV QINGDAO TECHNOLOGY
  • 国际专利分类:   H05K000/00
  • 专利详细信息:   ZA202203072-A 25 May 2022 H05K-000/00 202329 Pages: 12 English
  • 申请详细信息:   ZA202203072-A ZA003072 15 Mar 2022
  • 优先权号:   ZA003072

▎ 摘  要

NOVELTY - Preparation of one-dimensional yolk-shell nickel-doped void-cobalt(II,III)oxide-reduced graphene oxide (RGO) wave absorbent involves synthesizing nickel nanowires using nickel chloride hexahydrate as a nickel source and hydrazine hydrate as a reductant by a chemical reduction method, coating the outer side of nickel nanowires with a phenolic resin of resorcinol-formaldehyde (RF) layer through in-situ polymerization of resorcinol and formaldehyde to obtain one-dimensional nickel-doped RF nanowires, growing cobalt hydroxide nanosheets at the surface of the nickel-doped RF nanowires by an oil bath reflux method, annealing the cobalt hydroxide nanosheets into cobalt(II,III)oxide nanosheets in the air, removing the coated phenolic resin RF through a reaction with the air to obtain nickel-doped void-cobalt(II,III)oxide nanowires in a yolk-shell structure containing a flower-like surface, uniformly mixing the nanowires with a graphene suspension, and hydrothermally reacting. USE - Preparation of one-dimensional yolk-shell nickel-doped void-cobalt(II,III)oxide-reduced graphene oxide wave absorbent used for absorbing electromagnetic waves, improving wireless communication quality, and improving communication quality between aircraft and base station (all claimed). ADVANTAGE - The method provides wave absorbent having superior performance and excellent properties, uses flower-like cobalt(II,III)oxide nanosheets and RGO nanosheets to support dielectric loss, provides one-dimensional cavities in the nanowires to adjust the impedance matching and reduce a density of the composite, and lengthens loss path by reflecting and diffracting microwaves several times in the cavities, thus improving the wave absorbing property. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: improving wireless communication quality using the prepared wave absorbent; and improving communication quality between aircraft and base station using the prepared wave absorbent. DESCRIPTION OF DRAWING(S) - The drawing shows a flowchart of preparation of the wave absorbent. S101One-dimensional nickel nanowire preparation process S102Nickel-doped RF nanowire preparation process S103Nickel-doped void-cobalt oxide nanowire preparation process S104Nickel-doped void-cobalt oxide-reduced graphene oxide composite preparation process