• 专利标题:   Preparing polyvinyl alcohol-graphene oxide-polyaniline composite hydrogel used as e.g. adsorbent, involves dissolving polyvinol in deionized water, heating, stirring, adding graphene oxide solution into polyvinyl alcohol solution, adding oxidant into deionized water, thawing, freezing and thawing.
  • 专利号:   CN114752076-A
  • 发明人:   HUANG H, JI J, LI L, YU X, YAO W, XU C
  • 专利权人:   WUHAN INST TECHNOLOGY
  • 国际专利分类:   C08J003/075, C08J003/24, C08K003/04, C08L029/04, C08L079/02
  • 专利详细信息:   CN114752076-A 15 Jul 2022 C08J-003/075 202282 Chinese
  • 申请详细信息:   CN114752076-A CN10219790 08 Mar 2022
  • 优先权号:   CN10219790

▎ 摘  要

NOVELTY - Preparing polyvinyl alcohol-graphene oxide-polyaniline composite hydrogel comprises (i) dissolving 0.25 g polyvinol in deionized water, heating and stirring at 90℃, completely dissolving, and cooling to room temperature to obtain polyvinyl alcohol solution, (ii) adding graphene oxide solution into the polyvinyl alcohol solution, and stirring to disperse uniformly to obtain a graphene oxide and polyvinyl mixture, (iii) adding aniline monomer into the graphene oxide mixture, and uniformly stirring to disperse to obtain solution A, (iv) adding the oxidant into the deionized water, and dissolving to obtain the solution B, (v) cooling the solution A and second solution to 4℃, slowly dropping the second solution in first solution, stirring in the ice bath for 6 hours, placing for 12 hours under the condition of -30℃ and thawing at room temperature for 4 hours, freezing and thawing for a set number of times to obtain a polyvinyl alcohol-graphene oxide-polyaniline composite gel. USE - The method for preparing polyvinyl alcohol-graphene oxide-polyaniline composite hydrogel is used as adsorbent, and medicine carrier in the field of medicine treatment, biological detection. ADVANTAGE - The method provides polyvinyl alcohol-graphene oxide-polyaniline composite hydrogel with good mechanical ductility, can be bent, and the raw material cost is low, and the preparation process is simple. The method is simple, the components are effectively compounded on the substrate by simple operation, the moisture control can be realized by directional moisture stimulation, the power generation mode is environmentally-friendly, stable and sustainable, the temperature sensitivity is high, the response time is fast, does not need complex device, and has excellent compression and sensing performance.