• 专利标题:   Preparing pyridine type or pyrrole type iron-nitrogen site catalyst for fuel cell or metal air battery, by mixing and dispersing soluble iron salt, conductive carbon carrier and inorganic acid, polymerizing, calcining, washing and drying.
  • 专利号:   CN112827504-A, CN112827504-B
  • 发明人:   WU C, ZHANG N, ZHOU T, XIE Y
  • 专利权人:   UNIV CHINA SCI TECHNOLOGY
  • 国际专利分类:   B01J027/24, H01M004/90
  • 专利详细信息:   CN112827504-A 25 May 2021 B01J-027/24 202154 Pages: 19 Chinese
  • 申请详细信息:   CN112827504-A CN11642806 30 Dec 2020
  • 优先权号:   CN11642806

▎ 摘  要

NOVELTY - Method for preparing pyridine type or pyrrole type iron-nitrogen site catalyst, involves (a) mixing and dispersing soluble iron salt, nitrogen-containing polymer monomer, conductive carbon carrier and inorganic acid aqueous solution to obtain a suspension, (b) adding a polymerization initiator to the suspension, performing polymerization under stirring, separating, drying, and grinding to obtain iron-doped nitrogen-containing polymer precursor powder, and (c) calcining the precursor powder in an inert atmosphere or an ammonia atmosphere, acid washing and drying to obtain the desired catalyst. USE - The method is used for preparing pyridine type or pyrrole type iron-nitrogen site catalyst in oxygen reduction battery system for fuel cell or metal air battery (claimed). ADVANTAGE - The method uses cheap and easily available raw materials, has simple preparation process, and is suitable for industrial mass production. The high-purity iron-nitrogen site catalyst has excellent intrinsic catalytic activity, oxygen adsorption capacity, complete four-electron reaction selectivity, lower hydrogen peroxide yield, and excellent oxygen reduction performance. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a pyridine-type iron-nitrogen site catalyst prepared by the above method, where the molar ratio of iron and nitrogen atom in the pyridine-type iron-nitrogen site catalyst is 1:(4-12); and (2) a pyrrole-type iron-nitrogen site catalyst prepared by the above method, where the molar ratio of iron and nitrogen in the pyrrole-type iron-nitrogen site catalyst is 1:(4-12).