• 专利标题:   Preparation of graphene reinforced polymer porous sponge fiber for warmth retention fabric preparation and water treatment involves sonicating oxidized graphene in an ultrasonic bath at room temperature and dispersing graphite oxide.
  • 专利号:   CN103603081-A, CN103603081-B
  • 发明人:   GUO X, QU L, TIAN M, ZHANG X
  • 专利权人:   UNIV QINGDAO
  • 国际专利分类:   D01D001/02, D01D001/10, D01D005/06, D01D005/247, D01F011/00, D01F011/02, D01F011/06, D01F002/08, D01F006/54, D01F009/04
  • 专利详细信息:   CN103603081-A 26 Feb 2014 D01F-006/54 201434 Pages: 6 Chinese
  • 申请详细信息:   CN103603081-A CN10437548 24 Sep 2013
  • 优先权号:   CN10437548

▎ 摘  要

NOVELTY - A graphene reinforced polymer porous sponge fiber is prepared by (1) sonicating oxidized graphene in an ultrasonic bath at room temperature at 1-50 HZ for 0.5-1 hours, dispersing graphite oxide; (2) dissolving polymer in solvent to give polymer solution; (3) adding dispersed graphite oxide slowly while stirring, stirring for 4-8 hours to give homogeneous mixture of graphite oxide-polymer blend spinning solution; (4) standing to defoam for 8-12 hours, transferring to wet spinning apparatus, and spraying into coagulation bath solution. USE - Preparation of graphene reinforced polymer porous sponge fiber for warmth retention fabric preparation and water treatment. ADVANTAGE - Preparation process is simple, and low-cost, and has high intensity, good antistatic property, high elasticity, small density, and large specific surface area. DETAILED DESCRIPTION - A graphene reinforced polymer porous sponge fiber is prepared by (1) sonicating oxidized graphene in an ultrasonic bath at room temperature at 1-50 HZ for 0.5-1 hours, dispersing graphite oxide; (2) dissolving polymer in solvent to give polymer solution; (3) adding dispersed graphite oxide slowly while stirring, stirring for 4-8 hours to give homogeneous mixture of graphite oxide-polymer blend spinning solution; (4) standing to defoam for 8-12 hours, transferring to wet spinning apparatus, spraying into coagulation bath solution using spinning spinneret with pore size of 0.07-0.1 mm to obtain coagulation fibers, washing with water to give intermediate wet graphene oxide-polymer blend fibers; (5) adding 1-50% reducing agent with ratio of 1:10-1:50, reducing conditions to 30-95 degrees C for 0.5-2 hours, washed with water; (6) and freeze-drying or supercritical drying.