• 专利标题:   Molybdenum sulfide nanoribbon-graphene composite electrode used for lithium ion battery, comprises specified amount of nanoribbon/graphene composite, acetylene black, and polyvinylidene fluoride.
  • 专利号:   CN102709520-A, CN102709520-B
  • 发明人:   CHEN W, MA L, HUANG G, WANG Z
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   H01M004/136, H01M004/1397, H01M004/58
  • 专利详细信息:   CN102709520-A 03 Oct 2012 H01M-004/136 201311 Pages: 10 Chinese
  • 申请详细信息:   CN102709520-A CN10187851 08 Jun 2012
  • 优先权号:   CN10187851

▎ 摘  要

NOVELTY - A molybdenum sulfide nanoribbon-graphene composite electrode comprises nanoribbon/graphene composite (80-85 %mass), acetylene black (5-10 %mass), and polyvinylidene fluoride (10 %mass). USE - Molybdenum sulfide nanoribbon-graphene composite electrode is used for lithium ion battery. ADVANTAGE - The molybdenum sulfide nanoribbon-graphene composite electrode is manufactured economically using simple process. The battery containing the electrode has high battery characteristics, capacity, and cycle performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of molybdenum sulfide nanoribbon-graphene composite electrode. Graphene oxide (26.8-60.5 mmol/L) is ultrasonically dispersed in deionized water, cation surface active agent (0.01-0.05M) is added to dispersed mixture, and fully stirred. The obtained mixture is added to molybdenum thiosulfate, fully stirred, hydrazine hydrate (85 %mass) is dripped to the mixture, heated at 95 degrees C, continuously stirred and reacting for 5-8 hours to reflux. The mass ratio of graphene oxide to molybdenum thiosulfate is 1:0.5-1:4. The graphene oxide and molybdenum thiosulfate are reduced to molybdenum sulfide and graphene, separated an solid product is collected. The product is washed using deionized water, and then dried at 80 degrees C. The dried product is heated at 800 degrees C for 2 hours in nitrogen/hydrogen mixed atmosphere, to obtain molybdenum sulfide nanoribbon and graphene composite material. The obtained material is mixed with acetylene black and polyvinylidene fluoride, to obtain nano-composite electrode.