• 专利标题:   Preparing ultra-short carbon nanotube-graphene composite material for thermal management of electronic equipment, by obtaining water-soluble ultra-short carbon nanotube-graphene oxide dispersion by liquid-phase self-assembly method.
  • 专利号:   CN112209365-A
  • 发明人:   LUO W, LIU J, QUAN X, HUANG J
  • 专利权人:   UNIV GUANGDONG TECHNOLOGY
  • 国际专利分类:   C01B032/159, C01B032/168, C01B032/184
  • 专利详细信息:   CN112209365-A 12 Jan 2021 C01B-032/168 202112 Pages: 9 Chinese
  • 申请详细信息:   CN112209365-A CN10922969 04 Sep 2020
  • 优先权号:   CN10922969

▎ 摘  要

NOVELTY - Method for preparing ultra-short carbon nanotube-graphene composite material, involves (a) obtaining a water-soluble ultra-short carbon nanotube-graphene oxide dispersion by a liquid-phase self-assembly method of an ultra-short carbon nanotube solution with a length of 310-600 nm and a graphene oxide solution, (b) adding the reducing agent c in step (a), and preparing the ultrashort carbon nanotube-graphene composite material under the conditions of a temperature of 60-90 degrees C and a time of 30-120 minutes, where the liquid phase self-assembly method in step (a) comprises (a1) under the condition of 0-5 degrees C, ultrasonically dispersing the ultrashort carbon nanotube dispersion and the graphene oxide dispersion, (a2) continuously adding the ultra-short carbon nanotube dispersion to the graphene oxide dispersion under ultrasonic conditions of 0-5 degrees C, and (a3) continue the ultrasonic self-assembly to obtain the product. USE - The method is used for preparing ultra-short carbon nanotube-graphene composite material, which is used in the fields of thermal management of electronic equipment and thermal energy storage (all claimed). ADVANTAGE - The method is simple, and prepares relatively uniform ultra-short carbon nanotube-graphene composite materials. DETAILED DESCRIPTION - Method for preparing ultra-short carbon nanotube-graphene composite material, involves (a) obtaining a water-soluble ultra-short carbon nanotube-graphene oxide dispersion by a liquid-phase self-assembly method of an ultra-short carbon nanotube solution with a length of 310-600 nm and a graphene oxide solution, where the concentration of the ultra-short carbon nanotube solution 0.25-2 mg/ml, and the concentration of the graphene oxide solution is 0.25-2 mg/ml, (b) adding the reducing agent sodium borohydride in step (a), and preparing the ultrashort carbon nanotube-graphene composite material under the conditions of a temperature of 60-90 degrees C and a time of 30-120 minutes, where the liquid phase self-assembly method in step (a) comprises (a1) under the condition of 0-5 degrees C, ultrasonically dispersing the ultrashort carbon nanotube dispersion and the graphene oxide dispersion, (b) continuously adding the ultra-short carbon nanotube dispersion to the graphene oxide dispersion under ultrasonic conditions of 0-5 degrees C, and (c) after the dripping is completed, continue the ultrasonic self-assembly to obtain the product.