• 专利标题:   Preparing niobium pentoxide-reduced graphene oxide catalyst used for catalytic oxidation of thioether, by mixing graphene oxide dispersion with N-N'-dicyclohexylcarbodiimide, reacting, and adding modified graphene oxide to organic solution.
  • 专利号:   CN111450818-A
  • 发明人:   DAI Y, LIN J, PANG H, ZHANG L, SU Y, WEN M, MAI Y
  • 专利权人:   GUANGDONG RES INST PETROCHEMICAL IND
  • 国际专利分类:   B01J023/20, B01J035/10, B01J037/10, C07C315/02, C07C317/04, C07C317/10, C07C317/14, C07C317/22
  • 专利详细信息:   CN111450818-A 28 Jul 2020 B01J-023/20 202064 Pages: 8 Chinese
  • 申请详细信息:   CN111450818-A CN10161991 10 Mar 2020
  • 优先权号:   CN10161991

▎ 摘  要

NOVELTY - Method for preparing niobium pentoxide-reduced graphene oxide catalyst, involves (i) mixing graphene oxide dispersion with N-N'-dicyclohexylcarbodiimide, and reacting to obtain modified graphene oxide, and (ii) adding the modified graphene oxide to an organic solution of niobium pentachloride, and performing a hydrothermal reaction to obtain the product. USE - The method is used for preparing the catalyst for catalytic oxidation of thioether (all claimed). ADVANTAGE - The method provides the catalyst which has excellent catalytic selectivity for the oxidation of thioether to sulfoxide, and the sulfoxide selectivity is over 85%. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a niobium pentoxide-reduced graphene oxide catalyst, prepared by the above method; and (2) a method for catalytic oxidation of thioether, involving (a) adding sulfide and hydrogen peroxide to the organic solution of the catalyst, and (b) reacting to obtain sulfoxide and/or sulfone.