• 专利标题:   Electro-catalyzing degradation of cephalosporin by a nitrogen-doped graphene aerogel electrode comprises e. g. preparing nitrogen-doped graphene aerogel electrode material and grinding nitrogen-doped graphite aerogel electrode material.
  • 专利号:   CN108751352-A
  • 发明人:   XIN Q, ZANG Y, LIN J
  • 专利权人:   UNIV HANGZHOU DIANZI
  • 国际专利分类:   C02F001/46, C02F001/461, C02F101/30
  • 专利详细信息:   CN108751352-A 06 Nov 2018 C02F-001/46 201903 Pages: 5 Chinese
  • 申请详细信息:   CN108751352-A CN10516896 25 May 2018
  • 优先权号:   CN10516896

▎ 摘  要

NOVELTY - Electro-catalyzing degradation of cephalosporin by a nitrogen-doped graphene aerogel electrode comprises e. g. (i) preparing nitrogen-doped graphene aerogel electrode material; (ii) grinding the prepared nitrogen-doped graphite aerogel electrode material into a powder having particle size of 150-200 mesh, taking polytetrafluoroethylene as binder, nitrogen-doped graphene aerogel and acetylene black and physical vapor deposition material in a mass ratio of F=8:1:1, taking dimethylacetamide as solvent, stirring, applying to carbon paper, placing the coated carbon paper in oven at 80 degrees C, drying for 10 hours, taking the blank carbon paper with un-coated material as the cathode and using the silver/silver chloride electrode as the reference electrode; and (iii) preparing the cephalosporin in electrochemical reactor. USE - The method is useful for electro-catalyzing degradation of cephalosporin by a nitrogen-doped graphene aerogel electrode. ADVANTAGE - The method improves the active site and catalytic capacity of the material, and improves removal rate of cephalosporin and reduces running cost and is suitable for removal of cephalosporin antibiotic in water body. DETAILED DESCRIPTION - Electro-catalyzing degradation of cephalosporin by a nitrogen-doped graphene aerogel electrode comprises (i) preparing nitrogen-doped graphene aerogel electrode material; (ii) grinding the prepared nitrogen-doped graphite aerogel electrode material into a powder having particle size of 150-200 mesh, taking polytetrafluoroethylene as binder, nitrogen-doped graphene aerogel and acetylene black and physical vapor deposition material in a mass ratio of F=8:1:1, taking dimethylacetamide as solvent, stirring, applying to carbon paper, placing the coated carbon paper in oven at 80 degrees C, drying for 10 hours, taking the blank carbon paper with un-coated material as the cathode and using the silver/silver chloride electrode as the reference electrode; (iii) preparing the cephalosporin in electrochemical reactor, where the concentration of the cephalosporin is 1-20 mg/l; and (iv) turning on the power switch, setting the current density to 2-5 mA/cm2 and performing the sampling test to determine the removal rate of cephalosporin.