• 专利标题:   Catalyst useful for cycloaddition reaction of epoxide including ethylene oxide or propylene oxide, comprises graphene oxide, and hydrotalcite, where graphene oxide contains large number of electronegative groups.
  • 专利号:   CN111790365-A
  • 发明人:   LI D, GUO H, CHEN C, XIAO Y, JIA L, HOU B
  • 专利权人:   INST COAL CHEM CHINESE ACAD SCI
  • 国际专利分类:   B01J023/04, C07D317/36
  • 专利详细信息:   CN111790365-A 20 Oct 2020 B01J-023/04 202092 Pages: 8 Chinese
  • 申请详细信息:   CN111790365-A CN10638230 06 Jul 2020
  • 优先权号:   CN10638230

▎ 摘  要

NOVELTY - A catalyst comprises 10-50 wt.% graphene oxide and 40-90 wt.% hydrotalcite. The graphene oxide contains a large number of electronegative groups such as hydroxyl group, carboxylic acid group and carbonyl group. The cation of the hydrotalcite is composed of a divalent metal ion and a trivalent metal ion in a molar ratio of 2-5. USE - The catalyst is useful for cycloaddition reaction of epoxide including ethylene oxide or propylene oxide (all claimed). DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the catalyst, which involves: (1) dissolving precursors of divalent metal ion and trivalent metal ion in deionized water to prepare a solution (A) with a total concentration of 0.5-2 mol/l; (2) dissolving sodium hydroxide and sodium carbonate or potassium hydroxide and potassium carbonate in deionized water to prepare an alkaline solution (B) with a concentration of 1.5-2.5 mol/l, where the concentration of sodium carbonate or potassium carbonate is 0.2-0.5 mol/l, and the concentration of sodium hydroxide or potassium hydroxide is 1-2 mol/l; (3) adding graphene oxide to deionized water to obtain a mixture (C), where the mass of graphene oxide and deionized water is 1:200-10:100; (4) heat preserving at 40-60 degrees C under stirring conditions, carrying out co-current co-precipitation on the solutions (A) and (B) in the mixture (C) to obtain a slurry (D), where the pH of the precipitation reaction is 9-11, and the volume ratio of solution (A) and solution (C) is 1-4, and dynamically aging the slurry (D) under hydrothermal conditions at 60-90 degrees C for 6-15 hours to obtain a slurry (F); and (5) subjecting the slurry (F) to filtering, washing and drying at 100-120 degrees C for 10-20 hours.