• 专利标题:   Preparation of cathode for zinc ion battery, involves providing zinc cathode, pre-anode with vanadium dioxide as active material, electrolyte with zinc ion and hydrogen ion and performing pre-embedding ion treatment on pre-anode.
  • 专利号:   CN112736239-A, CN112736239-B
  • 发明人:   XU C, HUANG X, KANG F, LI J
  • 专利权人:   TSINGHUA SHENZHEN INT GRADUATE SCHOOL
  • 国际专利分类:   H01M010/36, H01M004/02, H01M004/04, H01M004/48
  • 专利详细信息:   CN112736239-A 30 Apr 2021 H01M-004/48 202150 Pages: 11 Chinese
  • 申请详细信息:   CN112736239-A CN11546169 23 Dec 2020
  • 优先权号:   CN11546169

▎ 摘  要

NOVELTY - Preparation of cathode involves providing pre-anode, zinc cathode, electrolyte, and electrochemical cell. The active material of pre-anode is vanadium dioxide. The electrolyte comprises water and soluble zinc salt. The pre-embedding ion treatment involves placing pre-anode, zinc cathode and electrolyte in electrochemical cell, assembling pre-embedded ion cell, treating pre-anode and embedding zinc ion and hydrogen ion in vanadium dioxide crystal structure to obtain vanadium dioxide pre-embedded zinc ion and hydrogen ion. The pre-anode obtained from pre-embedding ion-treatment serves as cathode in zinc ion battery. USE - Preparation of cathode of zinc ion battery (claimed). ADVANTAGE - The method enables preparing zinc ion battery cathode with excellent stability and durability. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) preparation of cathode of zinc ion battery, comprising pre-anode, zinc cathode, electrolyte, and electrochemical cell. The active material of pre-anode is vanadium dioxide. The electrolyte comprises water and soluble zinc salt. The pre-embedding ion treatment involves placing pre-anode, zinc cathode and electrolyte in electrochemical cell, assembling pre-embedded ion cell, treating pre-anode and embedding zinc ion and hydrogen ion in vanadium dioxide crystal structure to obtain vanadium dioxide pre-embedded zinc ion and hydrogen ion. The pre-anode obtained from pre-embedding ion-treatment serves as cathode in zinc ion battery. The chemical structural formula of vanadium dioxide of pre-embedded zinc ion and hydrogen ion is (ZnxHyVO2), x is content of pre-embedded zinc ion, x is more than 0 and less than or equal to 0.15, y is content of pre-embedded hydrogen ion, y is more than 0 and less than or equal to 0.8; and (2) zinc ion battery cathode, which comprises current collector and cathode film covered on the current collector. The cathode film contains vanadium dioxide pre-embedded zinc ion and hydrogen ion, electronic conducting agent and binder.