• 专利标题:   Preparing compound flexible conductive film of carbon nanotube-supported graphene-copper nanoparticles comprises e.g. preparing carbon nanotube conductive film by chemical vapor deposition, and cutting, dissolving graphene oxide.
  • 专利号:   CN108461177-A, CN108461177-B
  • 发明人:   BAO R, ZHAO W, FANG D, YI J, CHEN X
  • 专利权人:   UNIV KUNMING SCI TECHNOLOGY, UNIV KUNMING SCI TECHNOLOGY
  • 国际专利分类:   B82Y030/00, C01B032/168, H01B001/02, H01B001/04, H01B005/14
  • 专利详细信息:   CN108461177-A 28 Aug 2018 H01B-005/14 201861 Pages: 7 Chinese
  • 申请详细信息:   CN108461177-A CN10250732 26 Mar 2018
  • 优先权号:   CN10250732

▎ 摘  要

NOVELTY - Preparing compound flexible conductive film of carbon nanotube-supported graphene-copper nanoparticles comprises (i) preparing a carbon nanotube conductive film by chemical vapor deposition, and cutting it into a desired size, (ii) dissolving graphene oxide in deionized water, and ultrasonically dispersing to obtain graphene oxide suspension, (iii) dissolving copper salt in deionized water to obtain copper salt solution, and stirring, (iv) adding oxidized graphene suspension and copper salt solution, stirring, pouring in an atomizer, fixing carbon nano-tube film clamp, fixing, raising tubular high temperature area of the furnace temperature, precursor liquid fog drop generating by atomization region by high temperature chemical thermal decomposition, synthesizing cuprous oxide graphite alkene, diffusion, motion, load to the carrier of low temperature nucleation, growth area, and (v) centering, through a reducing atmosphere. USE - The method is useful for preparing compound flexible conductive film of carbon nanotube-supported graphene-copper nanoparticles. ADVANTAGE - The method: is simple and easy to operate; does not require large equipment; and has short process flow. DETAILED DESCRIPTION - Preparing compound flexible conductive film of carbon nanotube-supported graphene-copper nanoparticles comprises (i) preparing a carbon nanotube conductive film by chemical vapor deposition, and cutting it into a desired size, (ii) dissolving graphene oxide in deionized water at a ratio of 0.1-0.2 g/3000 ml, and ultrasonically dispersing for 0.2-2 hours to obtain graphene oxide suspension, (iii) dissolving 0.0017-0.01 mol/l copper salt in deionized water to obtain copper salt solution, and stirring uniformly under magnetic stirring at room temperature, (iv) adding oxidized graphene suspension and copper salt solution, stirring uniformly, pouring in an atomizer, fixing carbon nano-tube film clamp, fixing the tubular furnace low temperature area position at 150-250 degrees C, raising tubular high temperature area of the furnace temperature to 400-900 degrees C, at the same time open the two atomizer atomization mode, precursor liquid fog drop generating by atomization region by high temperature chemical thermal decomposition, synthesizing cuprous oxide graphite alkene, diffusion, motion, load to the carrier of low temperature nucleation, growth area to obtain carbon nano tube loaded with graphene nanometer cuprous oxide particles of the carrier, and (v) centering the compound carrier obtained in the step (iv) a the vacuum tubular furnace, through a reducing atmosphere at 250-300 degrees C for 3-8 hours.