• 专利标题:   Preparation of poly-1,5-diamino anthraquinone-modified graphene nanocomposite material used for, e.g. supercapacitor by preprocessing mixed sol solution, reacting in insulator, washing with deionized water, and adding to reducing solution.
  • 专利号:   CN103803531-A, CN103803531-B
  • 发明人:   WANG Y, WANG D, ZHANG C, WU X, HE D
  • 专利权人:   SHANGHAI NAT ENG RES CENT NANOTECHNOLOGY
  • 国际专利分类:   B82Y030/00, C01B031/04
  • 专利详细信息:   CN103803531-A 21 May 2014 C01B-031/04 201447 Pages: 7 Chinese
  • 申请详细信息:   CN103803531-A CN10456168 14 Nov 2012
  • 优先权号:   CN10456168

▎ 摘  要

NOVELTY - Preparation of poly-1,5-diamino anthraquinone-modified graphene nanocomposite material comprises dissolving protonic acid in N,N-dimethylformamide solution to obtain acid solution, dividing into two parts, adding one part with 1,5-diamino anthraquinone monomer and graphite oxide, and dispersing to obtain first sol solution; and dissolving oxidant in remaining acid solution, and dropping first sol solution; placing into insulator, washing with deionized water, adding to aqueous reducing solution, washing precipitate with deionized water, and centrifuging to obtain powder; and drying. USE - Method for preparation of poly-1,5-diamino anthraquinone-modified graphene nanocomposite material (claimed) used for secondary battery, supercapacitor, microwave absorbing coating, and sensors. ADVANTAGE - The method is simple and has low cost. DETAILED DESCRIPTION - Preparation of 1,5-diamino anthraquinone-modified graphene nanocomposite material comprises: (A) dissolving protonic acid in N,N-dimethylformamide solution to obtain acid, dividing into two parts, adding one part with 1,5-diamino anthraquinone monomer and graphite oxide, ultrasonically dispersing to obtain purple-brown first sol solution; and dissolving oxidant in another part of acid solution, and slowly dropping first sol solution to obtain mixed sol; (B) placing into constant temperature insulator, and reacting to obtain poly-1,5-diamino anthraquinone-modified graphene oxide composite powder intermediate product; (C) washing with deionized water to neutralize, adding to aqueous reducing solution while stirring, washing precipitate with deionized water, and centrifuging to obtain powder; and (D) drying to 50-70 degrees C in oven.