• 专利标题:   Rubber composite material comprises preset amount of styrene butadiene rubber, nitrile rubber, hydrogenated nitrile rubber and/or carboxyl nitrile rubber, graphene oxide coated with silver, and sulfur or organic peroxide.
  • 专利号:   CN103289138-A, CN103289138-B
  • 发明人:   TIAN M, ZHANG L, NING N, ZHANG X, ZOU H
  • 专利权人:   UNIV BEIJING CHEM TECHNOLOGY
  • 国际专利分类:   C08K013/06, C08K003/04, C08K009/02, C08L013/00, C08L015/00, C08L007/00, C08L009/02, C08L009/06
  • 专利详细信息:   CN103289138-A 11 Sep 2013 C08L-007/00 201427 Chinese
  • 申请详细信息:   CN103289138-A CN10199334 25 May 2013
  • 优先权号:   CN10199334

▎ 摘  要

NOVELTY - A rubber composite material comprises 100 pts. wt. rubber matrix, 0.1-5 pts. wt. conductive filler and 1.5-5 pts. wt. curing component. The rubber is styrene-butadiene rubber, nitrile rubber, hydrogenated nitrile rubber or carboxyl nitrile rubber. The conductive filler is graphene oxide coated with silver. The curing component is sulfur-based curing component or organic peroxide-based curing component, and is used for crosslinking the rubber matrix. USE - Rubber composite material (claimed). ADVANTAGE - The rubber composite material has excellent conductivity at low loading level, and low conducting percolation value. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of rubber composite material, which involves dissolving 0.1-0.3 %mass graphene oxide powder coated with silver in water, mixing uniformly with emulsion of rubber, dissolving and dispersing vulcanizing system, mixing the obtained emulsion, evaporating the emulsion at 0-55 degrees C using vacuum rotary evaporator to evaporate water, such that film is formed, dehydrating the film at 40-55 degrees C, preforming the obtained composite film, curing preformed composite film at 145-180 degrees C for 20-40 minutes, and hot pressing at 160-200 degrees C for 1-3 hours under pressure of 1-10 MPa.