• 专利标题:   Preparing graphene composite paper with high-strength and high-conductivity synthetic fiber comprises e.g. preparing synthetic fiber dispersant, mixing graphene slurry with synthetic fiber slurry, adding cation retention agent, stirring uniformly, drying, and hot pressing.
  • 专利号:   CN113430865-A, CN113430865-B
  • 发明人:   CAO S, WANG C, HUANG Q, WANG X
  • 专利权人:   UNIV SOUTH CHINA TECHNOLOGY
  • 国际专利分类:   D21H021/14, D21H015/10, D21H013/22, D21H013/26, D21H013/30, D21H013/24, D21H013/14, D21H021/52, D21H017/25, D21H017/55, D21H017/43, D21H017/42, D21H017/44, D21H017/45, D21H017/66, D21H011/12, D21H011/00, D21H017/24, D21H017/00, D21H021/08, D21H027/00
  • 专利详细信息:   CN113430865-A 24 Sep 2021 D21H-027/00 202191 Chinese
  • 申请详细信息:   CN113430865-A CN10656821 11 Jun 2021
  • 优先权号:   CN10656821

▎ 摘  要

NOVELTY - Preparing graphene composite paper with high-strength and high-conductivity synthetic fiber comprises (i) preparing synthetic fiber dispersant, where the synthetic fiber dispersant is dispersant 1, dispersant 2 or dispersant 3, (ii) dispersing synthetic fibers, water and synthetic fiber dispersant through a disintegrator to obtain synthetic fiber slurry, (iii) mixing the graphene slurry with the synthetic fiber slurry, adding a cation retention agent, and stirring uniformly to obtain a composite slurry, and (iv) forming the composite slurry by wet papermaking technology, drying, and hot pressing. The cationic polymer additive is a cationic polyacrylamide with a molecular weight of 1-2 million, polyethyleneimine with a molecular weight of 1-2 million, cationic guar gum with a molecular weight of 1-2 million or polyamide epichlorohydrin resin with a molecular weight of 100000-200000, and the anionic polymer additives are carboxymethyl cellulose. USE - The method is useful for preparing graphene composite paper with high-strength and high-conductivity synthetic fiber. ADVANTAGE - The composite paper has good uniformity high strength and good conductivity. The method is economical and has fast dispersion uniform dispersion little water. DETAILED DESCRIPTION - Preparing graphene composite paper with high-strength and high-conductivity synthetic fiber comprises (i) preparing synthetic fiber dispersant, where the synthetic fiber dispersant is dispersant 1, dispersant 2 or dispersant 3, where the dispersant 1 is prepared by taking dilute acid to dissolve chitosan to obtain a chitosan solution, dropping add dilute alkali solution until the pH of the system is 7-9 to obtain chitosan precipitation, washing the precipitate to neutrality and dispersing in water, the preparation of dispersant 2 comprises performing high-concentration beating of pulp fibers with a beating degree of 50-70degreesSR, adding water-soluble cationic polymer additives and anion polymer additives, and stirring for 5-15 minutes, the preparation of dispersant 3 comprises adding water-soluble cationic polymer additives or metal salts into the aqueous dispersion of nanocellulose, and stirring for 3-5 minutes, (ii) dispersing synthetic fibers, water and synthetic fiber dispersant through a disintegrator to obtain synthetic fiber slurry, (iii) mixing the graphene slurry with the synthetic fiber slurry, adding a cation retention agent, and stirring uniformly to obtain a composite slurry, and (iv) forming the composite slurry by wet papermaking technology, drying, and hot pressing. The cationic polymer additive is a cationic polyacrylamide with a molecular weight of 1-2 million, polyethyleneimine with a molecular weight of 1- 2 million, cationic guar gum with a molecular weight of 1-2 million or polyamide epichlorohydrin resin with a molecular weight of 100000-200000, the anionic polymer additives are carboxymethyl cellulose with a molecular weight of 200000-300000 or anionic polyacrylamide with a molecular weight of 100-200 million, the water-soluble cationic polymer additive is a cationic polyacrylamide with a molecular weight of 100000-200000, the polyethyleneimine with molecular weight 100000-200000 or polyamide epichlorohydrin resin with molecular weight 100000-200000 and the metal salt is a salt containing a metal ion, and the metal ion is a trivalent iron ion or a trivalent aluminum ion. An INDEPENDENT CLAIM is also included for composite paper prepared by the above mentioned method.