• 专利标题:   Preparation of graphene oxide nanoribbons involves adding concentrated sulfuric acid to PTFE-lined reactor, adding potassium permanganate and multiwalled carbon nanotubes, heating by sealing, adding hydrogen peroxide, washing and drying.
  • 专利号:   CN105016327-A, CN105016327-B
  • 发明人:   CHENG M, JIANG G, LIU Q, WANG J
  • 专利权人:   RES CENT ECO ENVIRONMENTAL SCI ACAD SIN, RES CENT ECO ENVIRONMENTAL SCI ACAD SIN
  • 国际专利分类:   B01J003/03, B82Y040/00, C01B031/04, C01B032/184
  • 专利详细信息:   CN105016327-A 04 Nov 2015 C01B-031/04 201603 Pages: 10 Chinese
  • 申请详细信息:   CN105016327-A CN10151849 16 Apr 2014
  • 优先权号:   CN10151849

▎ 摘  要

NOVELTY - Jacketed reactor made of stainless steel material, lined with PTFE, and including closed reaction space for safe reaction is used. Concentrated sulfuric acid is added to reactor lined with PTFE. Potassium permanganate and multiwalled carbon nanotubes (MWCNT) are added to the reactor, sealed, heated, ultrasonically oscillated, and 30% hydrogen peroxide is added, such that the volume ratio of hydrogen peroxide and concentrated sulfuric acid is 1:15. The resultant material is washed using hydrochloric acid and deionized water, and dried at room temperature to obtain graphene oxide nanoribbons. USE - Preparation of graphene oxide nanoribbons (claimed). ADVANTAGE - The method efficiently and safely provides high-quality graphene oxide nanoribbons having excellent water solubility and reduced structural defects, with high productivity and yield in short period of time without affecting the environment. DETAILED DESCRIPTION - Jacketed reactor made of stainless steel material, lined with PTFE, and including closed reaction space for safe reaction is used. Concentrated sulfuric acid is added to the reactor lined with PTFE, such that the volume of concentrated sulfuric acid and PTFE-lined reactor is 75:100. Potassium permanganate and MWCNT are added to the reactor in the ratio of 5:1. The volume ratio of MWCNT and concentrated sulfuric acid is 1:1 mg/mL. The reactor is sealed, heated at 60-70 degrees C at constant temperature for 3 hours, ultrasonically oscillated, and 30% hydrogen peroxide is added, such that the volume ratio of hydrogen peroxide and concentrated sulfuric acid is 1:15. The resultant material is washed using hydrochloric acid and deionized water, and dried at room temperature to obtain graphene oxide nanoribbons.