• 专利标题:   Three dimensional printing material comprises modified graphene, polyethylene terephthalate, nano polytetrafluoroethylene, nano silica and antioxidant, where modified graphene is made of graphene oxide and aqueous ammonia.
  • 专利号:   CN106751587-A, CN106751587-B
  • 发明人:   HUI X, XU X, XU N
  • 专利权人:   SHENZHEN MINGSCHIN HIGH POLYMER TECHNOLO
  • 国际专利分类:   B33Y070/00, C08K003/04, C08K003/36, C08K009/04, C08L027/18, C08L067/02
  • 专利详细信息:   CN106751587-A 31 May 2017 C08L-067/02 201745 Pages: 9 Chinese
  • 申请详细信息:   CN106751587-A CN11236196 28 Dec 2016
  • 优先权号:   CN11236196

▎ 摘  要

NOVELTY - Three dimensional printing material comprises 20-60 pts. wt. modified graphene, 30-50 pts. wt. polyethylene terephthalate, 2-8 pts. wt. nano polytetrafluoroethylene, 1-5 pts. wt. nano silica and 0.1-3 pts. wt. antioxidant, where modified graphene is made of graphene oxide, aqueous ammonia and polyethylene glycol diglycidyl ether. The mass ratio of graphene oxide and polyethylene glycol diglycidyl ether is 100:1-5. USE - Three dimensional printing material. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for producing three dimensional printing material, which involves: (A) dividing nano-polytetrafluoroethylene into two parts as first nano-polytetrafluoroethylene and second nano-polytetrafluoroethylene; (B) stirring and dispersing graphene oxide in ethanol solution to obtain graphene oxide dispersion, adding aqueous ammonia in dispersion and reacting at 95-105 degrees C for 55-65 minutes; (C) adding polyethylene glycol diglycidyl ether into it and reacting at 50-60 degrees C for 2-3 hours to obtain modified graphene; (D) mixing, heating and melting polyethylene terephthalate, first nano-polytetrafluoroethylene, the nano-silica and antioxidant to obtain mixed material; and (E) adding modified graphene and second nano-polytetrafluoroethylene to mixed material, stirring, extruding and granulating to obtain final product.