• 专利标题:   Anode used in lithium secondary battery, comprises current collector and anode active material layer placed on surface of current collector and comprising anode active material comprising magnesium-containing silicon oxide, conductive material comprising single-walled carbon nanotubes and binder.
  • 专利号:   WO2022060181-A1, KR2022039622-A, CN115552660-A, EP4148820-A1
  • 发明人:   OH I, SHIN S, KIM D, LEE Y, OH I G, SHIN S Y, LEE Y J, LI L, JIN D, SHEN S, WU Y
  • 专利权人:   LG ENERGY SOLUTION LTD, LG ENERGY SOLUTION LTD
  • 国际专利分类:   H01M010/052, H01M004/02, H01M004/131, H01M004/36, H01M004/48, H01M004/62
  • 专利详细信息:   WO2022060181-A1 24 Mar 2022 202228 Pages: 29
  • 申请详细信息:   WO2022060181-A1 WOKR012861 17 Sep 2021
  • 优先权号:   KR121829, CN80032845

▎ 摘  要

NOVELTY - Anode comprises a current collector and an anode active material layer placed on at least one surface of the current collector, and comprising (1) an anode active material comprising magnesium-containing silicon oxide and a graphene coating layer surrounding the surface of the magnesium-containing silicon oxide; (2) a conductive material comprising single-walled carbon nanotubes and (3) a binder, where the D/G band intensity ratio of graphene contained in the graphene coating layer is 0.8-1.5, and the D/G band intensity ratio of graphene is defined by the average of the ratio of the maximum peak intensity of D band at 1360 plus minus 50 cm-1 to the maximum peak intensity of G band at 1580 plus minus 50 cm-1, obtained by Raman spectroscopy of graphene. USE - The anode is useful in a lithium secondary battery (claimed). ADVANTAGE - The anode has excellent flexibility, initial capacity/efficiency and lifespan characteristics. DETAILED DESCRIPTION - Anode comprises a current collector and an anode active material layer placed on at least one surface of the current collector, and comprising (1) an anode active material comprising magnesium-containing silicon oxide of formula: SiOx, where x = greater than 0 and less than or equal to 2 and a graphene coating layer surrounding the surface of the magnesium-containing silicon oxide; (2) a conductive material comprising single-walled carbon nanotubes and (3) a binder, where the D/G band intensity ratio of graphene contained in the graphene coating layer is 0.8-1.5, and the D/G band intensity ratio of graphene is defined by the average of the ratio of the maximum peak intensity of D band at 1360 plus minus 50 cm-1 to the maximum peak intensity of G band at 1580 plus minus 50 cm-1, obtained by Raman spectroscopy of graphene.