• 专利标题:   Controlled growth of graphene film comprises preparing substrate of metal layer having phase diagram with carbon on surface to obtain homogeneous solid solution, exposing layer to controlled flow e.g. carbon atoms and changing the phase.
  • 专利号:   FR2937343-A1, WO2010043716-A2, WO2010043716-A3, EP2334839-A2, US2011198313-A1, FR2937343-B1, KR2011094178-A, JP2012505816-W, JP5816981-B2, US9206509-B2, KR1626181-B1
  • 发明人:   BARATON L, COJOCARU C S, PRIBAT D, COJOCARU C
  • 专利权人:   ECOLE POLYTECHNIQUE ETAB PUBLIC A CARACT, ECOLE POLYTECHNIQUE, CENT NAT RECH SCI, ECOLE POLYTECHNIQUE, CENT NAT RECH SCI
  • 国际专利分类:   C01B031/02, C30B001/10, C23C016/02, C23C016/26, C23C016/56, C30B025/02, C30B025/18, C30B029/00, C30B029/02, B05D003/02, B05D003/06, B05D003/10, B05D005/12, B32B037/14, B32B038/10, C23C014/48, C23C014/58
  • 专利详细信息:   FR2937343-A1 23 Apr 2010 C30B-001/10 201029 Pages: 24 French
  • 申请详细信息:   FR2937343-A1 FR005769 17 Oct 2008
  • 优先权号:   FR005769, KR711250

▎ 摘  要

NOVELTY - Controlled growth of graphene film comprises: preparing a substrate of a metal layer having a phase diagram with carbon, on surface, to obtain a homogeneous solid solution; exposing the metal layer to a controlled flow of carbon atoms/carbon radicals; and changing the phase of the mixture into two phases respectively of metal and graphite to form at least one lower graphene film located at interface:metal layer incorporating carbon atoms/substrate. USE - The process is useful for controlled growth of graphene film, in the field of electronics and visualization. ADVANTAGE - The process provides graphene film with good transparent and absorption property, good electrical conductivity and improved stability. The process is simple and reproducible. DETAILED DESCRIPTION - Controlled growth of graphene film comprises: preparing a substrate of a metal layer having a phase diagram with carbon at a threshold ratio of molar concentration of (CM/CM+Cc), where (CM) is molar concentration of metal in a metal mixture/carbon mixture and (Cc) is molar concentration of the carbon in the mixture, on the surface, for obtaining a homogeneous solid solution; exposing the metal layer to a controlled flow of carbon atoms or carbon radicals at a temperature such that the obtained molar concentration ratio is greater than the threshold ratio to obtain a solid solution of the carbon in the metal; and changing the phase of the mixture into two phases respectively of metal and graphite for forming at least one lower graphene film located at interface:metal layer incorporating carbon atoms/substrate.