• 专利标题:   Porous nitrogen-doped graphene carbon/ferrous oxide flexible composite material in lithium ion battery, has three-dimensional porous foam structure, and is prepared by preparing pure melamine foam and transferring into tubular furnace.
  • 专利号:   CN108199014-A
  • 发明人:   ZHU S, ZHAN S, MA M
  • 专利权人:   YINLONG NEW ENERGY CO LTD
  • 国际专利分类:   H01M004/36, H01M004/52, H01M004/62, H01M010/0525
  • 专利详细信息:   CN108199014-A 22 Jun 2018 H01M-004/36 201850 Pages: 8 Chinese
  • 申请详细信息:   CN108199014-A CN11312326 07 Dec 2017
  • 优先权号:   CN11312326

▎ 摘  要

NOVELTY - Porous nitrogen-doped graphene carbon/ferrous oxide flexible composite material has three-dimensional porous foam structure. USE - Porous nitrogen-doped graphene carbon/ferrous oxide flexible composite material used in lithium ion battery(claimed). ADVANTAGE - The porous nitrogen-doped graphene carbon/ferrous oxide flexible composite material has good flexibility, high conductivity and high specific capacity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing nitrogen-doped graphene carbon/ferrous oxide flexible composite material, which involves: (A) preparing pure melamine foam and transferring into tubular furnace under nitrogen atmosphere where calcining temperature is 300-1200 degrees C for 1-10 hours to obtain nitrogen-doped carbon foam substrate, preferably calcining temperature of melamine foam is 800-1200 degrees C for 3-10 hours; (B) adding ferrous oxide solution into nano graphene oxide solution according to certain proportion with stirring with mass of 5-10%; (C) adding nitrogen-doped carbon foam matrix which is 8-10% polyvinyl pyrrolidone with constant to obtain spinning stock solution by using receiving device; (D) adopting high pressure electrostatic spinning technology of spinning solution directly on carbon foam substrate to obtain porous nitrogen-doped graphene oxide polyvinyl pyrrolidone carbon/ferrous oxide composite material of multi-nitrogen-doped graphene oxide at high temperature tube type resistance furnace followed by high temperature carbonization; and (E) cooling to obtain porous nitrogen-doped graphene carbon/ferrous oxide/flexible composite material.