• 专利标题:   Preparing in-situ wear-resistant modified polyamide-imide molding compound, comprises e.g. mixing graphene oxide and diamine monomer, adding trimellitic anhydride acid chloride, performing in-situ polymerization reaction, adding catalyst to obtained pre-dispersed resin and chemical imidizing.
  • 专利号:   CN114752215-A
  • 发明人:   YOU R, GAN S, LI P, HUANG A, ZHENG Y, ZHANG Y, ZHAO C, HUANG Y, YANG H
  • 专利权人:   ZHUZHOU TIMES NEW MATERIAL TECHNOLOGY CO
  • 国际专利分类:   C08G073/10, C08K003/04, C08L027/16, C08L079/08
  • 专利详细信息:   CN114752215-A 15 Jul 2022 C08L-079/08 202279 Chinese
  • 申请详细信息:   CN114752215-A CN10596371 30 May 2022
  • 优先权号:   CN10596371

▎ 摘  要

NOVELTY - Preparing in-situ wear-resistant modified polyamide-imide molding compound, comprises (1) mixing graphene oxide and diamine monomer in an organic solvent and protecting by nitrogen to obtain dispersion liquid, and then adding trimellitic anhydride acid chloride in batches, carrying out in-situ polymerization reaction to obtain pre-dispersed resin, (2) adding catalyst to the pre-dispersed resin obtained in the step (1), carrying out chemical imidization treatment to obtain polyamide-imide solution with a high degree of cyclization, and (3) first separating polyamide-imide resin solution of step (2) to prepare resin powder, and then subjecting the resin powder to thermal imidization to obtain final product. USE - The in-situ wear-resistant modified polyamide-imide molding compound is useful in aerospace, military equipment, chemical equipment, and electronic appliances. ADVANTAGE - The method: utilizes graphene oxide, which can graft polyamide-imide molecular chains in situ; and graphene oxide and polyamide-imide are chemically bonded to improve the force between the polyamide-imide interface and reducing the polyamide-imide wear amount. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for in-situ wear-resistant modified polyamide-imide molding compound prepared by above method.