• 专利标题:   Polyurethane flame retardant composite material contains polyether polyol, toluene diisocyanate, nano-carbon sol, deionized water, dimethyl methylphosphonate, graphene oxide, ferrite, zirconia, zinc borate and stannous octoate.
  • 专利号:   CN107857987-A
  • 发明人:   CHENG X, ZHANG M, WEN Y
  • 专利权人:   HENAN HAINADE NEW MATERIALS CO LTD
  • 国际专利分类:   C08L075/08, C08K013/02, C08K003/04, C08K005/521, C08K003/22, C08K003/38, C08K005/098, C08K005/17, C08J009/08, C08G018/48, C08G018/76
  • 专利详细信息:   CN107857987-A 30 Mar 2018 C08L-075/08 201830 Pages: 7 Chinese
  • 申请详细信息:   CN107857987-A CN10843760 22 Sep 2016
  • 优先权号:   CN10843760

▎ 摘  要

NOVELTY - A polyurethane flame retardant composite material comprises 100 parts mass polyether polyol, 30-70 parts mass toluene diisocyanate, 0.01-0.5 part mass nano-carbon sol, 10-20 parts mass deionized water, 5-30 parts mass dimethyl methylphosphonate, 2-8 parts mass graphene oxide, 10-20 parts mass ferrite, 2-6 parts mass zirconia, 2-8 parts mass zinc borate, 0.02-0.4 part mass stannous octoate, 0.03-0.6 part mass triethylenediamine, 0.2-3 parts mass silicone surfactant and 1-10 parts mass sodium bicarbonate. USE - Polyurethane flame retardant composite material. ADVANTAGE - The low toxic polyurethane flame retardant composite material has wave absorption frequency distribution characteristics. DETAILED DESCRIPTION - Polyurethane flame retardant composite material comprises 100 parts mass polyether polyol, 30-70 parts mass toluene diisocyanate, 0.01-0.5 part mass nano-carbon sol, 10-20 parts mass deionized water, 5-30 parts mass dimethyl methylphosphonate, 2-8 parts mass graphene oxide, 10-20 parts mass ferrite, 2-6 parts mass zirconia, 2-8 parts mass zinc borate, 0.02-0.4 part mass stannous octoate, 0.03-0.6 part mass triethylenediamine, 0.2-3 parts mass silicone surfactant and 1-10 parts mass sodium bicarbonate. The hydroxy value of polyether polyol is 30-60 mg potassium hydroxide/g. The isocyanate index of toluene diisocyanate is 0.60-1.15. An INDEPENDENT CLAIM is included for preparation of polyurethane flame retardant composite material, which involves mixing polyether polyol, dimethyl methylphosphonate, nano-carbon sol, ferrite, zirconia, zinc borate, stannous octoate, triethylenediamine, deionized water and silicone surfactant, evenly stirring at room temperature, ultrasonically dispersing to obtain mixture (I), adding toluene diisocyanate to mixture (I), ultrasonically stirring for 5-10 minutes, then adding graphene oxide and sodium bicarbonate, quickly pouring into the mold, cooling to room temperature, foaming for 30-90 minutes to obtain wave absorbing material gel and freeze-drying to obtain final product.